| Asymmetric Construction of Six-Membered Rings by Cyclization of Allenes with Dinuclear Gold Catalysis | |
| Alternative Title | 通过金催化的联烯环化反应构建六元环的方法 |
| Chou YA(仇友爱)1; Zhou J(周静)1; Li JZ(李军召)1; Fu CL(傅春玲)1; Guo YL(郭寅龙)1; Wang HY(王浩洋)1; Ma SM(麻生明)1 | |
| 2015 | |
| Source Publication | Chem.-Eur. J.
 |
| Volume | 21Issue:45Pages:15939-15943 |
| Abstract | A simple and efficient method for the synthesis of 1,4-dihydroarenes by gold-catalyzed 6-endo cyclization of benzylic allenes has been developed. Furthermore, asymmetric hydroarylation of enantioenriched allenes has been realized to offer a practical and convergent approach to aromatic ring-fused six-membered cycles containing a chiral stereocenter such as 1,4-dihydronaphthalenes, 1,4-dihydrodibenzo[b,d]thiophenes, and 4,7-dihydrobenzo[b]thiophenes by applying dinuclear [(dppm)Au2Cl2] [dppm=methylenebis(diphenylphosphane)] combined with AgOTf as the catalyst to ensure the high efficiency of chirality transfer. ESI-MS has been applied to characterize some of the key reactive dinuclear gold intermediates successfully. |
| Subtype | 论文 |
| Subject Area | 金属有机化学 |
| DOI | 10.1002/chem.201503179 |
| URL | 查看原文 |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000363890700010 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sioc.ac.cn/handle/331003/39650 |
| Collection | 金属有机化学国家重点实验室 |
| Corresponding Author | Wang HY(王浩洋); Ma SM(麻生明) |
| Affiliation | 1.浙江大学 2.中科院上海有机化学研究所, 金属有机化学国家重点实验室 |
| Recommended Citation GB/T 7714 | Chou YA,Zhou J,Li JZ,et al. Asymmetric Construction of Six-Membered Rings by Cyclization of Allenes with Dinuclear Gold Catalysis[J]. Chem.-Eur. J.,2015,21(45):15939-15943. |
| APA | 仇友爱.,周静.,李军召.,傅春玲.,郭寅龙.,...&麻生明.(2015).Asymmetric Construction of Six-Membered Rings by Cyclization of Allenes with Dinuclear Gold Catalysis.Chem.-Eur. J.,21(45),15939-15943. |
| MLA | 仇友爱,et al."Asymmetric Construction of Six-Membered Rings by Cyclization of Allenes with Dinuclear Gold Catalysis".Chem.-Eur. J. 21.45(2015):15939-15943. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 2015545.pdf（510KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | Application Full Text | |
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