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学科主题: 金属有机化学
题名: A General, Practical Triethylborane-Catalyzed Reduction of Carbonyl Functions to Alcohols
其他题名: 一种普遍并实用的三乙基硼催化含官能团的羰基还原为醇的方法
作者: Peng DJ(彭东杰); Zhang MT(张岷涛); Huang Z(黄正)
通讯作者: 黄正
刊名: Chem.-Eur. J.
发表日期: 2015
DOI: 10.1002/chem.201502942
卷: 21, 期:42, 页:14737-14741
收录类别: SCI
文章类型: 论文
英文摘要: A combination of the abundant and low-cost triethylborane and sodium alkoxide generates a highly efficient catalyst for reduction of esters, as well as ketones and aldehydes, to alcohols using an inexpensive hydrosilane under mild conditions. The catalyst system exhibits excellent chemoselectivity and a high level of functional group tolerance. Mechanistic studies revealed a resting state of sodium triethylalkoxylborate that is the product of the reaction of BEt3 with sodium alkoxide. This borate species reacts with hydrosilane to form NaBEt3H, which rapidly reduces esters.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000363331900011
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39649
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 金属有机化学国家重点实验室

Recommended Citation:
Peng DJ,Zhang MT,Huang Z. A General, Practical Triethylborane-Catalyzed Reduction of Carbonyl Functions to Alcohols[J]. Chem.-Eur. J.,2015,21(42):14737-14741.
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