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A General, Practical Triethylborane-Catalyzed Reduction of Carbonyl Functions to Alcohols
Alternative Title一种普遍并实用的三乙基硼催化含官能团的羰基还原为醇的方法
Peng DJ(彭东杰); Zhang MT(张岷涛); Huang Z(黄正)
2015
Source PublicationChem.-Eur. J.
Volume21Issue:42Pages:14737-14741
AbstractA combination of the abundant and low-cost triethylborane and sodium alkoxide generates a highly efficient catalyst for reduction of esters, as well as ketones and aldehydes, to alcohols using an inexpensive hydrosilane under mild conditions. The catalyst system exhibits excellent chemoselectivity and a high level of functional group tolerance. Mechanistic studies revealed a resting state of sodium triethylalkoxylborate that is the product of the reaction of BEt3 with sodium alkoxide. This borate species reacts with hydrosilane to form NaBEt3H, which rapidly reduces esters.
Subtype论文
Subject Area金属有机化学
DOI10.1002/chem.201502942
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000363331900011
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39649
Collection金属有机化学国家重点实验室
Corresponding AuthorHuang Z(黄正)
Affiliation中科院上海有机化学研究所, 金属有机化学国家重点实验室
Recommended Citation
GB/T 7714
Peng DJ,Zhang MT,Huang Z. A General, Practical Triethylborane-Catalyzed Reduction of Carbonyl Functions to Alcohols[J]. Chem.-Eur. J.,2015,21(42):14737-14741.
APA 彭东杰,张岷涛,&黄正.(2015).A General, Practical Triethylborane-Catalyzed Reduction of Carbonyl Functions to Alcohols.Chem.-Eur. J.,21(42),14737-14741.
MLA 彭东杰,et al."A General, Practical Triethylborane-Catalyzed Reduction of Carbonyl Functions to Alcohols".Chem.-Eur. J. 21.42(2015):14737-14741.
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