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Dearomatization of Indoles via a Phenol-Directed Vanadium-Catalyzed Asymmetric Epoxidation and Ring-Opening Cascade
Alternative Title苯酚导向钒催化的不对称环氧化/开环串联反应实现吲哚去芳构化
Han L(韩龙)1; Zhang W(张玮)1; Shi XX(施小新)1; You SL(游书力)1
2015
Source PublicationAdv. Synth. Catal.
Volume357Issue:14-15Pages:3064-3068
AbstractAn enantioselective dearomatization of indole derivatives was realized by the complexes derived from the vanadium complex VO(acac)(2) and C-2-symmetric bis-hydroxamic acid (BHA) ligands. The reaction proceeded via asymmetric epoxidation and ring-opening by the linked phenol cascade, affording 5a, 6,10b, 11-tetrahydrochromeno[2,3-b]-indol-10b-ol derivatives in up to 83% yield and 98% ee under mild reaction conditions.
Subtype论文
Subject Area金属有机化学
DOI10.1002/adsc.201500557
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000363507400008
Citation statistics
Cited Times:15[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39648
Collection金属有机化学国家重点实验室
Corresponding AuthorYou SL(游书力)
Affiliation1.中科院上海有机化学研究所, 金属有机化学国家重点实验室
2.华东理工大学
Recommended Citation
GB/T 7714
Han L,Zhang W,Shi XX,et al. Dearomatization of Indoles via a Phenol-Directed Vanadium-Catalyzed Asymmetric Epoxidation and Ring-Opening Cascade[J]. Adv. Synth. Catal.,2015,357(14-15):3064-3068.
APA 韩龙,张玮,施小新,&游书力.(2015).Dearomatization of Indoles via a Phenol-Directed Vanadium-Catalyzed Asymmetric Epoxidation and Ring-Opening Cascade.Adv. Synth. Catal.,357(14-15),3064-3068.
MLA 韩龙,et al."Dearomatization of Indoles via a Phenol-Directed Vanadium-Catalyzed Asymmetric Epoxidation and Ring-Opening Cascade".Adv. Synth. Catal. 357.14-15(2015):3064-3068.
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