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学科主题: 金属有机化学
题名: Dearomatization of Indoles via a Phenol-Directed Vanadium-Catalyzed Asymmetric Epoxidation and Ring-Opening Cascade
其他题名: 苯酚导向钒催化的不对称环氧化/开环串联反应实现吲哚去芳构化
作者: Han L(韩龙)1; Zhang W(张玮)1; Shi XX(施小新)1; You SL(游书力)1
通讯作者: 游书力
刊名: Adv. Synth. Catal.
发表日期: 2015
DOI: 10.1002/adsc.201500557
卷: 357, 期:14-15, 页:3064-3068
收录类别: SCI
文章类型: 论文
英文摘要: An enantioselective dearomatization of indole derivatives was realized by the complexes derived from the vanadium complex VO(acac)(2) and C-2-symmetric bis-hydroxamic acid (BHA) ligands. The reaction proceeded via asymmetric epoxidation and ring-opening by the linked phenol cascade, affording 5a, 6,10b, 11-tetrahydrochromeno[2,3-b]-indol-10b-ol derivatives in up to 83% yield and 98% ee under mild reaction conditions.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000363507400008
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39648
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所, 金属有机化学国家重点实验室
2.华东理工大学

Recommended Citation:
Han L,Zhang W,Shi XX,et al. Dearomatization of Indoles via a Phenol-Directed Vanadium-Catalyzed Asymmetric Epoxidation and Ring-Opening Cascade[J]. Adv. Synth. Catal.,2015,357(14-15):3064-3068.
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