中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 金属有机化学国家重点实验室  > 期刊论文
学科主题: 金属有机化学
题名: A Two-Coordinate Cobalt(II) Imido Complex with NHC Ligation: Synthesis, Structure, and Reactivity
其他题名: 氮杂环卡宾配体支撑的两配位二价钴亚胺基配合物的合成、结构和反应性质的研究
作者: Du JZ(杜景祯)1; Wang LB(王林波)1; Xie MH(谢美华)1; Deng L(邓亮)1
通讯作者: 邓亮
刊名: Angew. Chem.-Int. Edit.
发表日期: 2015
DOI: 10.1002/anie.201505937
卷: 54, 期:43, 页:12640-12644
收录类别: SCI
文章类型: 论文
英文摘要: The synthesis, structural characterization, and reactivity of the first two-coordinate cobalt complex featuring a metal-element multiple bond [(IPr)Co(NDmp)] (4; IPr=1,3-bis(2',6'-diisopropylphenyl)imidazole-2-ylidene; Dmp=2,6-dimesitylphenyl) is reported. Complex 4 was prepared from the reaction of [(IPr)Co(eta(2)-vtms)(2)] (vtms=vinyltrimethylsilane) with DmpN(3). An X-ray diffraction study revealed its linear C-Co-N core and a short Co-N distance (1.691(6) angstrom). Spectroscopic characterization and calculation studies indicated the high-spin nature of 4 and the multiplebond character of the Co-N bond. Complex 4 effected group-transfer reactions to CO and ethylene to form isocyanide and imine, respectively. It also facilitated E-H (E=C, Si) sigma-bond activation of terminal alkyne and hydrosilanes to produce the corresponding cobalt(II) alkynyl and cobalt(II) hydride complexes as 1,2-addition products.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000363422700021
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39646
Appears in Collections:金属有机化学国家重点实验室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2015519.pdf(870KB)期刊论文作者接受稿开放获取View Download

作者单位: 1.中科院上海有机化学研究所, 金属有机化学国家重点实验室
2.安徽师范大学

Recommended Citation:
Du JZ,Wang LB,Xie MH,et al. A Two-Coordinate Cobalt(II) Imido Complex with NHC Ligation: Synthesis, Structure, and Reactivity[J]. Angew. Chem.-Int. Edit.,2015,54(43):12640-12644.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[杜景祯]'s Articles
[王林波]'s Articles
[谢美华]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[杜景祯]‘s Articles
[王林波]‘s Articles
[谢美华]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2015519.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace