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学科主题: 金属有机化学
题名: Rhodium(III)-Catalyzed Redox-Neutral C-H Annulation of Arylnitrones and Alkynes for the Synthesis of Indole Derivatives
其他题名: 铑催化的氧化中性的芳基硝酮与炔烃的C-H键环化反应合成吲哚衍生物
作者: Zhou Z(周志); Liu GX(刘桂霞); Chen Y(陈妍); Lu XY(陆熙炎)
通讯作者: 刘桂霞 ; 陆熙炎
刊名: Adv. Synth. Catal.
发表日期: 2015
DOI: 10.1002/adsc.201500580
卷: 357, 期:13, 页:2944-2950
收录类别: SCI
文章类型: 论文
英文摘要: By using a nitrone as the oxidizing directing group, a mild, practical and efficient rhodium(III)-catalyzed C-H functionalization for the synthesis of indole derivatives has been developed. This reaction obviates the need for an external oxidant and shows good functional group tolerance. The employment of a sterically hindered Mes group on the carbon center of the nitrone is crucial to produce indoles in high yield.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000362527100023
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39644
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 金属有机化学国家重点实验室

Recommended Citation:
Zhou Z,Liu GX,Chen Y,et al. Rhodium(III)-Catalyzed Redox-Neutral C-H Annulation of Arylnitrones and Alkynes for the Synthesis of Indole Derivatives[J]. Adv. Synth. Catal.,2015,357(13):2944-2950.
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