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Three-Coordinate Iron(II) Dialkenyl Compound with NHC Ligation: Synthesis, Structure, and Reactivity
其他题名氮杂环卡宾配体支撑的三配位铁烯基化合物的合成、结构和反应性质研究
Liu YS(刘月盛); Wang L(王磊); Deng L(邓亮)
2015
发表期刊Organometallics
卷号34期号:17页码:4401-4407
摘要The reaction of [(IPr2Me2)(2)FePh2] with PhC equivalent to CPh furnished a three-coordinate iron(II) dialkenyl complex, [(IPr2Me2)Fe(sigma-CPh=CPh2)(2)] (1, IPr2Me2 = 1,3-diisopropy1-4,5-dimethylimidazol-2-ylidene), that represents a rare example of isolable low-coordinate iron alkenyl complexes with a high-spin ground state. Complex 1 was characterized by H-1 NMR spectroscopy, solution magnetic susceptibility measurement, Mossbauer spectroscopy, single-crystal X-ray diffraction study, and elemental analyses. A reactivity study revealed the reactions of 1 with PhCh(2)C1 to produce cross-coupling product Ph2C=CPhCh(2)Ph (2), with [Cp2Fe]-[BAr4F] to yield Ph2C=CPh CPh=CPh2 (3), and with CO, 2,6-dimethylphenyl isocyanide, and phenyl azide to produce novel iron(0) and iron(II) complexes 4-6 bearing triphenylvinyl-derived ligands. These transformations demonstrated the high reactivity of the low-coordinate iron alkenyl complex.
文章类型论文
学科领域金属有机化学
DOI10.1021/acs.organomet.5b00632
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收录类别SCI
语种英语
WOS记录号WOS:000361341800027
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文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/39640
专题金属有机化学国家重点实验室
通讯作者Deng L(邓亮)
作者单位中科院上海有机化学研究所, 金属有机化学国家重点实验室
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GB/T 7714
Liu YS,Wang L,Deng L. Three-Coordinate Iron(II) Dialkenyl Compound with NHC Ligation: Synthesis, Structure, and Reactivity[J]. Organometallics,2015,34(17):4401-4407.
APA 刘月盛,王磊,&邓亮.(2015).Three-Coordinate Iron(II) Dialkenyl Compound with NHC Ligation: Synthesis, Structure, and Reactivity.Organometallics,34(17),4401-4407.
MLA 刘月盛,et al."Three-Coordinate Iron(II) Dialkenyl Compound with NHC Ligation: Synthesis, Structure, and Reactivity".Organometallics 34.17(2015):4401-4407.
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