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学科主题: 金属有机化学
题名: Gold(I)-catalyzed cycloisomerization of vinylidenecyclopropane-enes via carbene or non-carbene processes
其他题名: 金催化的亚乙烯基环丙烷的环异构化反应
作者: Li DY(李德尧)1; Wei Y(魏音)1; MAREK ILAN1; Tang XY(唐翔鹰)1; Shi M(施敏)1
通讯作者: 唐翔鹰 ; 施敏
刊名: Chem. Sci.
发表日期: 2015
DOI: 10.1039/c5sc01806d
卷: 6, 期:10, 页:5519-5525
收录类别: SCI
文章类型: 论文
英文摘要: Gold catalyzed cycloisomerization of aromatic ring tethered vinylidenecyclopropane-enes provides a divergent synthetic protocol for the construction of O-containing fused heterocycles through controllable carbene or non-carbene related processes. The carbene induced process features a new amphiphilic strategy to generate a gold carbene via a rearrangement of vinylidenecyclopropane. Whereas, the electronic effect of the ortho-substituents switches the reaction mode onto the non-carbene related process, from which five-or six-membered rings are selectively produced through allyl-migration.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000361212000020
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39639
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所, 金属有机化学国家重点实验室
2.以色列理工学院

Recommended Citation:
Li DY,Wei Y,MAREK ILAN,et al. Gold(I)-catalyzed cycloisomerization of vinylidenecyclopropane-enes via carbene or non-carbene processes[J]. Chem. Sci.,2015,6(10):5519-5525.
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