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Synthesis and Chiroptical Properties of Double-Helical (M)- and (P)-o-Oligophenylenes
Alternative Title手性寡聚四苯并环辛四烯的合成和光化学性质
Chen JX(陈景行)1; Han JW(韩建伟)1; Huang NZ(黄乃正)1
Source PublicationOrg. Lett.
AbstractAll of the M and P isomers of optically pure oligophenylenes with 6, 8, 10, and 12 phenyl rings were synthesized and fully characterized. The Suzuki cross-coupling reaction has been revealed to be a viable strategy in the syntheses of tetraphenylene derivatives, which, together with the copper-mediated oxidative cross-coupling reaction, were employed in the quest for the oligophenylenes. X-ray diffraction analysis in combination with specific rotation and circular dichroism spectroscopy unambiguously identified the unique covalent double-helical frameworks of these oligophenylene molecules.
Subject Area金属有机化学
Indexed BySCI
WOS IDWOS:000361087200044
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Document Type期刊论文
Corresponding AuthorHuang NZ(黄乃正)
Affiliation1.中科院上海有机化学研究所, 沪港合成化学联合实验室
Recommended Citation
GB/T 7714
Chen JX,Han JW,Huang NZ. Synthesis and Chiroptical Properties of Double-Helical (M)- and (P)-o-Oligophenylenes[J]. Org. Lett.,2015,17(17):4296-4299.
APA 陈景行,韩建伟,&黄乃正.(2015).Synthesis and Chiroptical Properties of Double-Helical (M)- and (P)-o-Oligophenylenes.Org. Lett.,17(17),4296-4299.
MLA 陈景行,et al."Synthesis and Chiroptical Properties of Double-Helical (M)- and (P)-o-Oligophenylenes".Org. Lett. 17.17(2015):4296-4299.
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