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学科主题: 金属有机化学
题名: Synthesis and Chiroptical Properties of Double-Helical (M)- and (P)-o-Oligophenylenes
其他题名: 手性寡聚四苯并环辛四烯的合成和光化学性质
作者: Chen JX(陈景行)1; Han JW(韩建伟)1; Huang NZ(黄乃正)1
通讯作者: 黄乃正
刊名: Org. Lett.
发表日期: 2015
DOI: 10.1021/acs.orglett.5b02102
卷: 17, 期:17, 页:4296-4299
收录类别: SCI
文章类型: 论文
英文摘要: All of the M and P isomers of optically pure oligophenylenes with 6, 8, 10, and 12 phenyl rings were synthesized and fully characterized. The Suzuki cross-coupling reaction has been revealed to be a viable strategy in the syntheses of tetraphenylene derivatives, which, together with the copper-mediated oxidative cross-coupling reaction, were employed in the quest for the oligophenylenes. X-ray diffraction analysis in combination with specific rotation and circular dichroism spectroscopy unambiguously identified the unique covalent double-helical frameworks of these oligophenylene molecules.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000361087200044
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39638
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所, 沪港合成化学联合实验室
2.香港中文大学

Recommended Citation:
Chen JX,Han JW,Huang NZ. Synthesis and Chiroptical Properties of Double-Helical (M)- and (P)-o-Oligophenylenes[J]. Org. Lett.,2015,17(17):4296-4299.
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