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学科主题: 金属有机化学
题名: Linear and T-Shaped Iron(I) Complexes Supported by N-Heterocyclic Carbene Ligands: Synthesis and Structure Characterization
其他题名: 氮杂环卡宾配体支撑的直线型、T字型一价铁配合物的合成和结构表征
作者: 欧阳振武1; Du JZ(杜景祯)1; Wang L(王磊)1; KNEEBONE JARED L1; NEIDIG MICHAEL L1; Deng L(邓亮)1
通讯作者: 邓亮
刊名: Inorg. Chem.
发表日期: 2015
DOI: 10.1021/acs.inorgchem.5b01522
卷: 54, 期:17, 页:8808-8816
收录类别: SCI
文章类型: 论文
英文摘要: The use of the N-heterocyclic carbene (NHC) ligands 1,3-bis(2',6'-diethylphenyl)-4,5-(CH2)(4)-imidazol-2-ylidene (cyIDep), 1,3-bis(2',6'-diethylphenyl)-imidazolin-2-ylidene (sIDep), and its N-mesityl analogue sIMes enables the preparation of the two-coordinate homoleptic iron(I)-NHC complexes [(cyIDep)(2)Fe][BAr4F] (3, Ar-F denoted for 3,5-di(trifluoromethyl)phenyl) and [(sIDep)(2)Fe][BAr4F] (4) and the T-shaped iron(I)-NHC complex [(sIMes)(2)Fe(THF)]-[BPh4] (5, THF = tetrahydrofuran). Complexes 3-5 were prepared via the sequential protocol of control reduction of iron(II) dihalides by KC8 in the presence of the corresponding NHC ligands followed by halide-abstraction with NaBAr4. Spectroscopic characterization, including single-crystal X-ray diffraction studies and Fe-57 Mossbauer spectroscopy, in combination with density functional theory calculations, suggest their high-spin nature. Solution property study (absorption spectroscopy and cyclic voltammetry) indicates that 3 and 5 keep their corresponding two- and three-coordinate nature in THF solution, and 4 might reversibly coordinate a THF molecule to form, presumably, the T-shaped species [(sIDep)(2)Fe(THF)][BAr4F]. The isolation of 3 and 4 demonstrates the accessibility of homoleptic two-coordinate iron(I)-NHC complexes.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000361085800078
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39637
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所, 金属有机化学国家重点实验室
2.美国罗切斯特大学

Recommended Citation:
欧阳振武,Du JZ,Wang L,et al. Linear and T-Shaped Iron(I) Complexes Supported by N-Heterocyclic Carbene Ligands: Synthesis and Structure Characterization[J]. Inorg. Chem.,2015,54(17):8808-8816.
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