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Gold(I)-Catalyzed Tandem Transformation with Diynes: Rapid Access to Linear Cyclopentenone-Fused Polycyclic Molecules
Alternative Title金催化的高效合成含环戊烯酮多环化合物
Yu CJ(于丛军); Chen B(陈斌); Zhou T(周添); Tian QS(田青杉); Zhang GZ(张国柱)
2015
Source PublicationAngew. Chem.-Int. Edit.
Volume54Issue:37Pages:10903-10907
AbstractAn efficient and convenient synthesis of useful linear cyclopentenone-fused polycyclic compounds has been achieved through a novel gold(I)-catalyzed transformation of diynes. The method demonstrates high product yields and tolerates of a wide variety of important functional groups. Gold-vinylidene formation, methoxy group migration, and Nazarov-type cyclization are proposed to be the key steps in the reaction pathway. The synthetic utility of this method is demonstrated by converting the product to eight-membered-ring-fused compound.
Subtype论文
Subject Area金属有机化学
DOI10.1002/anie.201503599
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000360628500036
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39636
Collection金属有机化学国家重点实验室
Corresponding AuthorZhang GZ(张国柱)
Affiliation中科院上海有机化学研究所, 金属有机化学国家重点实验室
Recommended Citation
GB/T 7714
Yu CJ,Chen B,Zhou T,et al. Gold(I)-Catalyzed Tandem Transformation with Diynes: Rapid Access to Linear Cyclopentenone-Fused Polycyclic Molecules[J]. Angew. Chem.-Int. Edit.,2015,54(37):10903-10907.
APA 于丛军,陈斌,周添,田青杉,&张国柱.(2015).Gold(I)-Catalyzed Tandem Transformation with Diynes: Rapid Access to Linear Cyclopentenone-Fused Polycyclic Molecules.Angew. Chem.-Int. Edit.,54(37),10903-10907.
MLA 于丛军,et al."Gold(I)-Catalyzed Tandem Transformation with Diynes: Rapid Access to Linear Cyclopentenone-Fused Polycyclic Molecules".Angew. Chem.-Int. Edit. 54.37(2015):10903-10907.
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