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学科主题: 金属有机化学
题名: Gold(I)-Catalyzed Tandem Transformation with Diynes: Rapid Access to Linear Cyclopentenone-Fused Polycyclic Molecules
其他题名: 金催化的高效合成含环戊烯酮多环化合物
作者: Yu CJ(于丛军); Chen B(陈斌); Zhou T(周添); Tian QS(田青杉); Zhang GZ(张国柱)
通讯作者: 张国柱
刊名: Angew. Chem.-Int. Edit.
发表日期: 2015
DOI: 10.1002/anie.201503599
卷: 54, 期:37, 页:10903-10907
收录类别: SCI
文章类型: 论文
英文摘要: An efficient and convenient synthesis of useful linear cyclopentenone-fused polycyclic compounds has been achieved through a novel gold(I)-catalyzed transformation of diynes. The method demonstrates high product yields and tolerates of a wide variety of important functional groups. Gold-vinylidene formation, methoxy group migration, and Nazarov-type cyclization are proposed to be the key steps in the reaction pathway. The synthetic utility of this method is demonstrated by converting the product to eight-membered-ring-fused compound.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000360628500036
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39636
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 金属有机化学国家重点实验室

Recommended Citation:
Yu CJ,Chen B,Zhou T,et al. Gold(I)-Catalyzed Tandem Transformation with Diynes: Rapid Access to Linear Cyclopentenone-Fused Polycyclic Molecules[J]. Angew. Chem.-Int. Edit.,2015,54(37):10903-10907.
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