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Catalytic alkane dehydrogenations
Alternative Title催化烷烃脱氢
Zhang YX(张宇轩)1; Yao WB(姚武冰)1; Fang HQ(方华权)1; Hu AG(胡爱国)1; Huang Z(黄正)1
Source PublicationSci. Bull.
AbstractOlefins find widespread applications in the synthesis of polyolefins and fine chemicals. With an increasing demand for olefins, the technologies for alkane dehydrogenation have drawn much attention. Several types of heterogeneous catalysts have found applications in industry for the dehydrogenation of light alkanes, mainly ethane, propane, and butane. In the past three decades, a number of transition-metal complexes, particularly pincer-ligated iridium complexes, have been developed as the homogeneous catalysts for alkane dehydrogenations. The homogeneous catalyst systems operate under much milder conditions compared with the heterogeneous systems, and some systems exhibit good activity and high regioselectivity in dehydrogenation of alkanes longer than butane.
Subject Area金属有机化学
Indexed BySCI
WOS IDWOS:000359557600002
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Document Type期刊论文
Corresponding AuthorHu AG(胡爱国); Huang Z(黄正)
2.中科院上海有机化学研究所, 金属有机化学国家重点实验室
Recommended Citation
GB/T 7714
Zhang YX,Yao WB,Fang HQ,et al. Catalytic alkane dehydrogenations[J]. Sci. Bull.,2015,60(15):1316-1331.
APA 张宇轩,姚武冰,方华权,胡爱国,&黄正.(2015).Catalytic alkane dehydrogenations.Sci. Bull.,60(15),1316-1331.
MLA 张宇轩,et al."Catalytic alkane dehydrogenations".Sci. Bull. 60.15(2015):1316-1331.
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