中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 金属有机化学国家重点实验室  > 期刊论文
学科主题: 金属有机化学
题名: Efficient production of methanol and diols via the hydrogenation of cyclic carbonates using copper-silica nanocomposite catalysts
其他题名: 铜-硅酸盐纳米复合催化剂催化的环状碳酸酯氢化高效制备甲醇和二醇
作者: Liu HL(刘海龙)1; Huang ZW(黄志伟)1; Han ZB(韩召斌)1; Ding KL(丁奎岭)1; Liu HC(刘海超)1; Xia CG(夏春谷)1; Chen J(陈经)1
通讯作者: 丁奎岭 ; 夏春谷 ; 陈经
刊名: Green Chem.
发表日期: 2015
DOI: 10.1039/c5gc00810g
卷: 17, 期:8, 页:4281-4290
收录类别: SCI
文章类型: 论文
英文摘要: Copper-silica nanocomposite catalysts with a uniform Cu dispersion prepared by a precipitation-gel method have been found to be highly efficient in the heterogeneous catalytic hydrogenation of CO2-derived cyclic carbonates, providing an indirect but practical approach for the transformation of CO2 to methanol with the co-production of diols under relatively mild conditions. The catalysts possessed remarkable stability in both batch and fixed-bed continuous flow reactors especially after promotion with B2O3. The reaction was found to depend sensitively on the Cu particle size, the surface acidity-basicity and the Cu valence of the catalysts. The synergetic effect between balanced Cu-0 and Cu+ sites was considered to play a critical role in attaining high yields of methanol and diols.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000358887300023
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39629
Appears in Collections:金属有机化学国家重点实验室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2015413.pdf(870KB)期刊论文作者接受稿开放获取View Download

作者单位: 1.中科院兰州化学物理研究所
2.中科院上海有机化学研究所, 金属有机化学国家重点实验室
3.中国科学院大学

Recommended Citation:
Liu HL,Huang ZW,Han ZB,et al. Efficient production of methanol and diols via the hydrogenation of cyclic carbonates using copper-silica nanocomposite catalysts[J]. Green Chem.,2015,17(8):4281-4290.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[刘海龙]'s Articles
[黄志伟]'s Articles
[韩召斌]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[刘海龙]‘s Articles
[黄志伟]‘s Articles
[韩召斌]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2015413.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace