中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 金属有机化学国家重点实验室  > 期刊论文
学科主题: 金属有机化学
题名: Ligand-enabled Ir-catalyzed intermolecular diastereoselective and enantioselective allylic alkylation of 3-substituted indoles
其他题名: 配体促进的铱催化3-取代吲哚分子间非对映选择性和对映选择性烯丙基烷基化反应
作者: Zhang X(张霄)1; Liu WB(刘文博)1; Tu HF(涂航飞)1; You SL(游书力)1
通讯作者: 游书力
刊名: Chem. Sci.
发表日期: 2015
DOI: 10.1039/c5sc01772f
卷: 6, 期:8, 页:4525-4529
收录类别: SCI
文章类型: 论文
英文摘要: An Ir-catalyzed asymmetric allylic alkylation of 3-substituted indoles is reported. The reaction provides indoline products containing multiple contiguous stereocenters with high site-, regio-, diastereo- and enantioselectivities in one step from a wide range of readily available starting materials. The key to this method is the high level of diastereocontrol enabled by an iridium catalyst derived from a N-aryl phosphoramidite ligand (Me-THQphos, 1c).
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000357931700015
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39626
Appears in Collections:金属有机化学国家重点实验室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2015400.pdf(826KB)期刊论文作者接受稿开放获取View Download

作者单位: 1.中科院上海有机化学研究所, 金属有机化学国家重点实验室
2.天津化学化工协同创新中心

Recommended Citation:
Zhang X,Liu WB,Tu HF,et al. Ligand-enabled Ir-catalyzed intermolecular diastereoselective and enantioselective allylic alkylation of 3-substituted indoles[J]. Chem. Sci.,2015,6(8):4525-4529.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[张霄]'s Articles
[刘文博]'s Articles
[涂航飞]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[张霄]‘s Articles
[刘文博]‘s Articles
[涂航飞]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2015400.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace