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Ligand-enabled Ir-catalyzed intermolecular diastereoselective and enantioselective allylic alkylation of 3-substituted indoles
Alternative Title配体促进的铱催化3-取代吲哚分子间非对映选择性和对映选择性烯丙基烷基化反应
Zhang X(张霄)1; Liu WB(刘文博)1; Tu HF(涂航飞)1; You SL(游书力)1
2015
Source PublicationChem. Sci.
Volume6Issue:8Pages:4525-4529
AbstractAn Ir-catalyzed asymmetric allylic alkylation of 3-substituted indoles is reported. The reaction provides indoline products containing multiple contiguous stereocenters with high site-, regio-, diastereo- and enantioselectivities in one step from a wide range of readily available starting materials. The key to this method is the high level of diastereocontrol enabled by an iridium catalyst derived from a N-aryl phosphoramidite ligand (Me-THQphos, 1c).
Subtype论文
Subject Area金属有机化学
DOI10.1039/c5sc01772f
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000357931700015
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39626
Collection金属有机化学国家重点实验室
Corresponding AuthorYou SL(游书力)
Affiliation1.中科院上海有机化学研究所, 金属有机化学国家重点实验室
2.天津化学化工协同创新中心
Recommended Citation
GB/T 7714
Zhang X,Liu WB,Tu HF,et al. Ligand-enabled Ir-catalyzed intermolecular diastereoselective and enantioselective allylic alkylation of 3-substituted indoles[J]. Chem. Sci.,2015,6(8):4525-4529.
APA 张霄,刘文博,涂航飞,&游书力.(2015).Ligand-enabled Ir-catalyzed intermolecular diastereoselective and enantioselective allylic alkylation of 3-substituted indoles.Chem. Sci.,6(8),4525-4529.
MLA 张霄,et al."Ligand-enabled Ir-catalyzed intermolecular diastereoselective and enantioselective allylic alkylation of 3-substituted indoles".Chem. Sci. 6.8(2015):4525-4529.
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