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学科主题: 金属有机化学
题名: Enantioselective Synthesis of Pyrrole-Based Spiro- and Polycyclic Derivatives by Iridium-Catalyzed Asymmetric Allylic Dearomatization and Controllable Migration Reactions
其他题名: 通过铱催化的不对称烯丙基去芳构化和可控的迁移反应不对称合成螺环和多环吡咯衍生物
作者: Zhuo CX(卓春祥); Cheng Q(程强); Liu WB(刘文博); Zhao Q(赵强); You SL(游书力)
通讯作者: 游书力
刊名: Angew. Chem.-Int. Edit.
发表日期: 2015
DOI: 10.1002/anie.201502259
卷: 54, 期:29, 页:8475-8479
收录类别: SCI
文章类型: 论文
英文摘要: The first highly diastereo- and enantioselective synthesis of five-membered spiro-2H-pyrroles was achieved using an Ir-catalyzed asymmetric allylic dearomatization reaction. The spiro-2H-pyrrole derivatives readily undergo a controllable and stereospecific allylic migration under acid catalysis, providing polycyclic pyrrole derivatives in excellent yields and ee values. Additionally, the novel Ir-complex K1, derived from [Ir(cod) Cl](2) (cod= 1,5-cyclooctadiene) and N-benzhydryl-N-phenyldinaphthophosphoramidite (BHPphos), showed excellent control of both diastereo- and enantioselectivities.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000358050300029
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39620
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 金属有机化学国家重点实验室

Recommended Citation:
Zhuo CX,Cheng Q,Liu WB,et al. Enantioselective Synthesis of Pyrrole-Based Spiro- and Polycyclic Derivatives by Iridium-Catalyzed Asymmetric Allylic Dearomatization and Controllable Migration Reactions[J]. Angew. Chem.-Int. Edit.,2015,54(29):8475-8479.
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