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Thermal characterization of the promising energetic material TKX-50
Alternative TitleThermal characterization of the promising energetic material TKX-50
Huang HF(黄海丰); Shi YM(石亚猛); Yang J(杨军)
2015
Source PublicationJ. Therm. Anal. Calorim.
Volume121Issue:2Pages:705-709
AbstractThe thermal behavior of dihydroxylammonium 5,50-bistetrazole-1,1'-diolate (TKX-50) was measured by differential scanning calorimetry (DSC), thermal gravimetric analysis-Fourier transform infrared spectroscopy (TG-FTIR) and thermal gravimetric analysisdifferential scanning calorimetry-mass spectrometry (TG-DSC-MS). The critical temperature of thermal explosion (T-b) and the initial decomposition temperature (T-p0) were determined to be 523.39 and 513.80 K, respectively. The apparent activation energy (E) and preexponential factor (A) of the exothermic decomposition reaction, and activation entropy (Delta S-not equal), activation enthalpy (Delta H-not equal), activation Gibbs free energy (Delta G(not equal)) at T-P0 of the reaction and the critical temperature of thermal explosion (T-b) were calculated: E-K = 237.59 kJ mol(-1), E-O = 234.11 kJ mol(-1), Delta S-not equal = 209.83 J K-1 mol(-1), Delta H-not equal = 233.32 kJ mol(-1), Delta G(not equal) = 126.53 kJ mol(-1). TG-DSC-FTIR/MS analysis of thermal decomposition products of TKX-50 reveals that the main decomposition products are N-2, H2O, NH3, NH2, N2O and NO.
Subtype论文
Subject Area有机化学
DOI10.1007/s10973-015-4472-9
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000357676500021
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39618
Collection金属有机化学国家重点实验室
Corresponding AuthorYang J(杨军)
Affiliation中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Huang HF,Shi YM,Yang J. Thermal characterization of the promising energetic material TKX-50[J]. J. Therm. Anal. Calorim.,2015,121(2):705-709.
APA 黄海丰,石亚猛,&杨军.(2015).Thermal characterization of the promising energetic material TKX-50.J. Therm. Anal. Calorim.,121(2),705-709.
MLA 黄海丰,et al."Thermal characterization of the promising energetic material TKX-50".J. Therm. Anal. Calorim. 121.2(2015):705-709.
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