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学科主题: 有机化学
题名: Thermal characterization of the promising energetic material TKX-50
其他题名: Thermal characterization of the promising energetic material TKX-50
作者: Huang HF(黄海丰); Shi YM(石亚猛); Yang J(杨军)
通讯作者: 杨军
刊名: J. Therm. Anal. Calorim.
发表日期: 2015
DOI: 10.1007/s10973-015-4472-9
卷: 121, 期:2, 页:705-709
收录类别: SCI
文章类型: 论文
英文摘要: The thermal behavior of dihydroxylammonium 5,50-bistetrazole-1,1'-diolate (TKX-50) was measured by differential scanning calorimetry (DSC), thermal gravimetric analysis-Fourier transform infrared spectroscopy (TG-FTIR) and thermal gravimetric analysisdifferential scanning calorimetry-mass spectrometry (TG-DSC-MS). The critical temperature of thermal explosion (T-b) and the initial decomposition temperature (T-p0) were determined to be 523.39 and 513.80 K, respectively. The apparent activation energy (E) and preexponential factor (A) of the exothermic decomposition reaction, and activation entropy (Delta S-not equal), activation enthalpy (Delta H-not equal), activation Gibbs free energy (Delta G(not equal)) at T-P0 of the reaction and the critical temperature of thermal explosion (T-b) were calculated: E-K = 237.59 kJ mol(-1), E-O = 234.11 kJ mol(-1), Delta S-not equal = 209.83 J K-1 mol(-1), Delta H-not equal = 233.32 kJ mol(-1), Delta G(not equal) = 126.53 kJ mol(-1). TG-DSC-FTIR/MS analysis of thermal decomposition products of TKX-50 reveals that the main decomposition products are N-2, H2O, NH3, NH2, N2O and NO.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000357676500021
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39618
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
Huang HF,Shi YM,Yang J. Thermal characterization of the promising energetic material TKX-50[J]. J. Therm. Anal. Calorim.,2015,121(2):705-709.
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