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学科主题: 金属有机化学
题名: Copper-Catalyzed Trifluoromethylazidation of Alkynes: Efficient Access to CF3-Substituted Azirines and Aziridines
其他题名: 铜催化炔烃的三氟甲基叠氮化反应: 高效合成含CF3的氮丙啶
作者: Wang F(王飞)1; Zhu N(朱娜)1; Chen PH(陈品红)1; Ye JX(叶金星)1; Liu GS(刘国生)1
通讯作者: 刘国生
刊名: Angew. Chem.-Int. Edit.
发表日期: 2015
DOI: 10.1002/anie.201503412
卷: 54, 期:32, 页:9356-9360
收录类别: SCI
文章类型: 论文
英文摘要: A novel method for convenient access to CF3-containing azirines has been developed, and involves a copper-catalyzed trifluoromethylazidation of alkynes and a photocatalyzed rearrangement. Both terminal and internal alkynes are compatible with the mild reaction conditions, thus delivering the CF3-containing azirines in moderate to good yields. The azirines can be converted into various CF3-substituted aziridines.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000358621500039
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39615
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所, 金属有机化学国家重点实验室
2.华东理工大学

Recommended Citation:
Wang F,Zhu N,Chen PH,et al. Copper-Catalyzed Trifluoromethylazidation of Alkynes: Efficient Access to CF3-Substituted Azirines and Aziridines[J]. Angew. Chem.-Int. Edit.,2015,54(32):9356-9360.
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