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Copper-Catalyzed Trifluoromethylazidation of Alkynes: Efficient Access to CF3-Substituted Azirines and Aziridines
Alternative Title铜催化炔烃的三氟甲基叠氮化反应: 高效合成含CF3的氮丙啶
Wang F(王飞)1; Zhu N(朱娜)1; Chen PH(陈品红)1; Ye JX(叶金星)1; Liu GS(刘国生)1
2015
Source PublicationAngew. Chem.-Int. Edit.
Volume54Issue:32Pages:9356-9360
AbstractA novel method for convenient access to CF3-containing azirines has been developed, and involves a copper-catalyzed trifluoromethylazidation of alkynes and a photocatalyzed rearrangement. Both terminal and internal alkynes are compatible with the mild reaction conditions, thus delivering the CF3-containing azirines in moderate to good yields. The azirines can be converted into various CF3-substituted aziridines.
Subtype论文
Subject Area金属有机化学
DOI10.1002/anie.201503412
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000358621500039
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39615
Collection金属有机化学国家重点实验室
Corresponding AuthorLiu GS(刘国生)
Affiliation1.中科院上海有机化学研究所, 金属有机化学国家重点实验室
2.华东理工大学
Recommended Citation
GB/T 7714
Wang F,Zhu N,Chen PH,et al. Copper-Catalyzed Trifluoromethylazidation of Alkynes: Efficient Access to CF3-Substituted Azirines and Aziridines[J]. Angew. Chem.-Int. Edit.,2015,54(32):9356-9360.
APA 王飞,朱娜,陈品红,叶金星,&刘国生.(2015).Copper-Catalyzed Trifluoromethylazidation of Alkynes: Efficient Access to CF3-Substituted Azirines and Aziridines.Angew. Chem.-Int. Edit.,54(32),9356-9360.
MLA 王飞,et al."Copper-Catalyzed Trifluoromethylazidation of Alkynes: Efficient Access to CF3-Substituted Azirines and Aziridines".Angew. Chem.-Int. Edit. 54.32(2015):9356-9360.
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