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学科主题: 金属有机化学
题名: Kinetic Resolution of Unsymmetrical Acyclic Allyl Carbonates Using Trimethylsilyl Cyanide via Palladium-Catalyzed Asymmetric Allylic Alkylation
其他题名: 使用三甲硅腈通过钯催化不对称烯丙基烷基化反应对非对称烯丙基碳酸酯的动力学拆分
作者: Bai DC(白大昌)1; Wang WY(王皖颖)1; Ding CH(丁昌华)1; Hou XL(侯雪龙)1
通讯作者: 侯雪龙
刊名: Synlett
发表日期: 2015
DOI: 10.1055/s-0034-1378709
卷: 26, 期:11, 页:1510-1514
收录类别: SCI
文章类型: 论文
英文摘要: The kinetic resolution of 1,3-disubstituted unsymmetrical allylic substrates with TMSCN as the nucleophile was realized via palladium-catalyzed asymmetric allylic alkylation, providing optically active allylic substrates and ,-unsaturated nitriles in good yield and enantioselectivity.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000356859200016
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39612
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所, 金属有机化学国家重点实验室
2.中科院上海有机化学研究所, 沪港合成化学联合实验室

Recommended Citation:
Bai DC,Wang WY,Ding CH,et al. Kinetic Resolution of Unsymmetrical Acyclic Allyl Carbonates Using Trimethylsilyl Cyanide via Palladium-Catalyzed Asymmetric Allylic Alkylation[J]. Synlett,2015,26(11):1510-1514.
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