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学科主题: 金属有机化学
题名: Gold(I)-Catalyzed 1,3-O-Transposition Reactions: Ynesulfonamides to Ynamides
其他题名: 金催化的1,3-氧迁移反应: 从炔磺酰胺到炔酰胺
作者: Li DY(李德尧); Wei Y(魏音); Shi M(施敏)
通讯作者: 魏音 ; 施敏
刊名: Eur. J. Org. Chem.
发表日期: 2015
DOI: 10.1002/ejoc.201500604
期: 19, 页:4108-4113
收录类别: SCI
文章类型: 论文
英文摘要: The gold-catalyzed 1,3-O-transposition reaction of ynesulfonamides provides a practical synthetic protocol for the synthesis of ynamides under mild conditions. This is the first 1,3-O-transposition example of ynesulfonamides in which a heteroatom is attached to the alkynyl terminal. A plausible mechanism is been proposed on the basis of O-18-labeling and control experiments as well as DFT calculation. By simple treatment, the obtained ynamides can easily be transformed into useful products.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000356870600009
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39611
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 金属有机化学国家重点实验室

Recommended Citation:
Li DY,Wei Y,Shi M. Gold(I)-Catalyzed 1,3-O-Transposition Reactions: Ynesulfonamides to Ynamides[J]. Eur. J. Org. Chem.,2015(19):4108-4113.
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