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Gold(I)-Catalyzed 1,3-O-Transposition Reactions: Ynesulfonamides to Ynamides
Alternative Title金催化的1,3-氧迁移反应: 从炔磺酰胺到炔酰胺
Li DY(李德尧); Wei Y(魏音); Shi M(施敏)
Source PublicationEur. J. Org. Chem.
AbstractThe gold-catalyzed 1,3-O-transposition reaction of ynesulfonamides provides a practical synthetic protocol for the synthesis of ynamides under mild conditions. This is the first 1,3-O-transposition example of ynesulfonamides in which a heteroatom is attached to the alkynyl terminal. A plausible mechanism is been proposed on the basis of O-18-labeling and control experiments as well as DFT calculation. By simple treatment, the obtained ynamides can easily be transformed into useful products.
Subject Area金属有机化学
Indexed BySCI
WOS IDWOS:000356870600009
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Document Type期刊论文
Corresponding AuthorWei Y(魏音); Shi M(施敏)
Affiliation中科院上海有机化学研究所, 金属有机化学国家重点实验室
Recommended Citation
GB/T 7714
Li DY,Wei Y,Shi M. Gold(I)-Catalyzed 1,3-O-Transposition Reactions: Ynesulfonamides to Ynamides[J]. Eur. J. Org. Chem.,2015(19):4108-4113.
APA 李德尧,魏音,&施敏.(2015).Gold(I)-Catalyzed 1,3-O-Transposition Reactions: Ynesulfonamides to Ynamides.Eur. J. Org. Chem.(19),4108-4113.
MLA 李德尧,et al."Gold(I)-Catalyzed 1,3-O-Transposition Reactions: Ynesulfonamides to Ynamides".Eur. J. Org. Chem. .19(2015):4108-4113.
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