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学科主题: 金属有机化学
题名: Enantioselective annulation of enals with 2-naphthols by triazolium salts derived from L-phenylalanine
其他题名: 苯丙氨酸衍生的三唑盐催化的烯醛和2-萘酚的不对称环化反应
作者: Li GT(李国泰)1; Gu Q(顾庆)1; You SL(游书力)1
通讯作者: 游书力
刊名: Chem. Sci.
发表日期: 2015
DOI: 10.1039/c5sc00731c
卷: 6, 期:7, 页:4273-4278
收录类别: SCI
文章类型: 论文
英文摘要: A series of chiral triazolium salts have been synthesized from methyl L-phenylalaninate hydrochloride. The NHCs derived from this class of novel triazolium salts were found to be highly efficient catalysts in the annulation reaction of enals and 2-naphthols. These reactions proceeded with high chemoselectivity and wide substrate scope affording enantioenriched beta-arylsplitomicins in good yields with up to 96% ee.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000356176200076
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39610
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 1.华东理工大学
2.中科院上海有机化学研究所, 金属有机化学国家重点实验室
3.天津化学化工协同创新中心

Recommended Citation:
Li GT,Gu Q,You SL. Enantioselective annulation of enals with 2-naphthols by triazolium salts derived from L-phenylalanine[J]. Chem. Sci.,2015,6(7):4273-4278.
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