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Enantioselective annulation of enals with 2-naphthols by triazolium salts derived from L-phenylalanine
Alternative Title苯丙氨酸衍生的三唑盐催化的烯醛和2-萘酚的不对称环化反应
Li GT(李国泰)1; Gu Q(顾庆)1; You SL(游书力)1
2015
Source PublicationChem. Sci.
Volume6Issue:7Pages:4273-4278
AbstractA series of chiral triazolium salts have been synthesized from methyl L-phenylalaninate hydrochloride. The NHCs derived from this class of novel triazolium salts were found to be highly efficient catalysts in the annulation reaction of enals and 2-naphthols. These reactions proceeded with high chemoselectivity and wide substrate scope affording enantioenriched beta-arylsplitomicins in good yields with up to 96% ee.
Subtype论文
Subject Area金属有机化学
DOI10.1039/c5sc00731c
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000356176200076
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39610
Collection金属有机化学国家重点实验室
Corresponding AuthorYou SL(游书力)
Affiliation1.华东理工大学
2.中科院上海有机化学研究所, 金属有机化学国家重点实验室
3.天津化学化工协同创新中心
Recommended Citation
GB/T 7714
Li GT,Gu Q,You SL. Enantioselective annulation of enals with 2-naphthols by triazolium salts derived from L-phenylalanine[J]. Chem. Sci.,2015,6(7):4273-4278.
APA 李国泰,顾庆,&游书力.(2015).Enantioselective annulation of enals with 2-naphthols by triazolium salts derived from L-phenylalanine.Chem. Sci.,6(7),4273-4278.
MLA 李国泰,et al."Enantioselective annulation of enals with 2-naphthols by triazolium salts derived from L-phenylalanine".Chem. Sci. 6.7(2015):4273-4278.
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