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Copper-Catalyzed Intermolecular Asymmetric Propargylic Dearomatization of Indoles
Alternative Title铜催化吲哚的分子间不对称丙炔化去芳构化反应
Shao W(邵稳)1; Li H(李贺)1; Liu C(刘川)1; Liu CJ(刘晨江)1; You SL(游书力)1
Source PublicationAngew. Chem.-Int. Edit.
AbstractThe first copper-catalyzed intermolecular dearomatization of indoles by an asymmetric propargylic substitution reaction was developed. This method provides a highly efficient synthesis of versatile furoindoline and pyrroloindoline derivatives containing a quaternary carbon stereogenic center and a terminal alkyne moiety with up to 86% yield and 98% ee.
Subject Area金属有机化学
Indexed BySCI
WOS IDWOS:000356390900043
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Document Type期刊论文
Corresponding AuthorLiu CJ(刘晨江); You SL(游书力)
Affiliation1.中科院上海有机化学研究所, 金属有机化学国家重点实验室
Recommended Citation
GB/T 7714
Shao W,Li H,Liu C,et al. Copper-Catalyzed Intermolecular Asymmetric Propargylic Dearomatization of Indoles[J]. Angew. Chem.-Int. Edit.,2015,54(26):7684-7687.
APA 邵稳,李贺,刘川,刘晨江,&游书力.(2015).Copper-Catalyzed Intermolecular Asymmetric Propargylic Dearomatization of Indoles.Angew. Chem.-Int. Edit.,54(26),7684-7687.
MLA 邵稳,et al."Copper-Catalyzed Intermolecular Asymmetric Propargylic Dearomatization of Indoles".Angew. Chem.-Int. Edit. 54.26(2015):7684-7687.
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