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Palladium-Catalyzed Asymmetric Arylation of C(sp(3))-H Bonds of Aliphatic Amides: Controlling Enantioselectivity Using Chiral Phosphoric Amides/Acids
Alternative Title钯催化脂肪族酰胺sp3碳氢键的不对称芳基化: 使用手性磷酰胺/磷酸控制立体选择性
Yan SB(晏邵佰); Zhang S(张松); Duan WL(段伟良)
2015
Source PublicationOrg. Lett.
Volume17Issue:10Pages:2458-2461
AbstractEnantioselective arylation of secondary beta-C(sp(3))-H bonds of 8-aminoquinoline amides was realized with a palladium catalyst. Chiral phosphoric amides and acids were used for the first time to control the stereoselectivity at the C-H bond cleavage step in the C-H activation reactions.
Subtype论文
Subject Area金属有机化学
DOI10.1021/acs.orglett.5b00968
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000354908300043
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39604
Collection金属有机化学国家重点实验室
Corresponding AuthorDuan WL(段伟良)
Affiliation中科院上海有机化学研究所, 金属有机化学国家重点实验室
Recommended Citation
GB/T 7714
Yan SB,Zhang S,Duan WL. Palladium-Catalyzed Asymmetric Arylation of C(sp(3))-H Bonds of Aliphatic Amides: Controlling Enantioselectivity Using Chiral Phosphoric Amides/Acids[J]. Org. Lett.,2015,17(10):2458-2461.
APA 晏邵佰,张松,&段伟良.(2015).Palladium-Catalyzed Asymmetric Arylation of C(sp(3))-H Bonds of Aliphatic Amides: Controlling Enantioselectivity Using Chiral Phosphoric Amides/Acids.Org. Lett.,17(10),2458-2461.
MLA 晏邵佰,et al."Palladium-Catalyzed Asymmetric Arylation of C(sp(3))-H Bonds of Aliphatic Amides: Controlling Enantioselectivity Using Chiral Phosphoric Amides/Acids".Org. Lett. 17.10(2015):2458-2461.
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