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学科主题: 金属有机化学
题名: Copper-Catalyzed Intermolecular Trifluoromethylthiocyanation of Alkenes: Convenient Access to CF3-Containing Alkyl Thiocyanates
其他题名: 铜催化烯烃的分子间三氟甲基硫氰化反应: 简便合成含CF3的烷基硫氰
作者: Liang ZL(梁兆利); Wang F(王飞); Chen PH(陈品红); Liu GS(刘国生)
通讯作者: 刘国生
刊名: Org. Lett.
发表日期: 2015
DOI: 10.1021/acs.orglett.5b00939
卷: 17, 期:10, 页:2438-2441
收录类别: SCI
文章类型: 论文
英文摘要: A highly selective and efficient approach for the direct trifluoromethylthiocyanation of alkenes has been developed using trimethylsilyl isothiocyanate (TMSNCS) as the thiocyanating agent and Togni reagent as the CF3 source in the presence of copper(I) catalyst. Both activated and unactivated alkenes work well to deliver various CF3-containing thiocyanates.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000354908300038
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39603
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 金属有机化学国家重点实验室

Recommended Citation:
Liang ZL,Wang F,Chen PH,et al. Copper-Catalyzed Intermolecular Trifluoromethylthiocyanation of Alkenes: Convenient Access to CF3-Containing Alkyl Thiocyanates[J]. Org. Lett.,2015,17(10):2438-2441.
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