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Asymmetric Dearomatization of Naphthols via a Rh-Catalyzed C(sp(2))-H Functionalization/Annulation Reaction
Alternative Title铑催化C(sp2)-H官能化/环化反应实现萘酚的不对称去芳构化
Zheng J(郑军); Wang SB(王少博); Zheng C(郑超); You SL(游书力)
2015
Source PublicationJ. Am. Chem. Soc.
Volume137Issue:15Pages:4880-4883
AbstractA Rh-catalyzed enantioselective dearomatization of 1-aryl-2-naphthols with internal alkynes via C-H functionalization reaction was achieved. In the presence of a chiral Cp/Rh catalyst and combined oxidants of Cu(OAc)(2) and air (oxygen), various highly enantioenriched spirocyclic enones bearing an all-carbon quaternary stereogenic center could be synthesized in 33-98% yields with up to 97:3 er.
Subtype论文
Subject Area金属有机化学
DOI10.1021/jacs.5b01707
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000353606700002
Citation statistics
Cited Times:132[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39599
Collection金属有机化学国家重点实验室
Corresponding AuthorYou SL(游书力)
Affiliation中科院上海有机化学研究所, 金属有机化学国家重点实验室
Recommended Citation
GB/T 7714
Zheng J,Wang SB,Zheng C,et al. Asymmetric Dearomatization of Naphthols via a Rh-Catalyzed C(sp(2))-H Functionalization/Annulation Reaction[J]. J. Am. Chem. Soc.,2015,137(15):4880-4883.
APA 郑军,王少博,郑超,&游书力.(2015).Asymmetric Dearomatization of Naphthols via a Rh-Catalyzed C(sp(2))-H Functionalization/Annulation Reaction.J. Am. Chem. Soc.,137(15),4880-4883.
MLA 郑军,et al."Asymmetric Dearomatization of Naphthols via a Rh-Catalyzed C(sp(2))-H Functionalization/Annulation Reaction".J. Am. Chem. Soc. 137.15(2015):4880-4883.
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