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学科主题: 金属有机化学
题名: Silane-Functionalized N-Heterocyclic Carbene-Cobalt Complexes Containing a Five-Coordinate Silicon with a Covalent Co-Si Bond
其他题名: 具有共价钴硅键的五配位硅的硅基官能团化的氮杂环卡宾钴配合物
作者: Sun J(孙键)1; Ou C(欧翀)1; Wang C(王超)1; UCHIYAMA MASANOBU1; Deng L(邓亮)1
通讯作者: 王超 ; 邓亮
刊名: Organometallics
发表日期: 2015
DOI: 10.1021/acs.organomet.5b00114
卷: 34, 期:8, 页:1546-1551
收录类别: SCI
文章类型: 论文
英文摘要: Novel cobalt complexes featuring five-coordinate silicon centers with a covalent CoSi bond, i.e., [(SiN2C)Co(OPy)] complexes (SiN2C = tetradentate silane-anchored bis(pyridine)-N-heterocyclic carbene (NHC) ligand, OPy = 2-pyridonato), were prepared by reaction of bidentate hydrosilyl-NHC-supported cobalt(II) complexes with 2-pyridone and characterized by H-1, C-13, and Si-29 NMR, single-crystal X-ray diffraction, and elemental analyses. Theoretical calculations support a covalent nature of the CoSi interaction, in contrast to the metal -> Si dative bonds in metallasilatranes.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000353668700015
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39598
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所, 金属有机化学国家重点实验室
2.日本理化学研究所
3.日本东京大学

Recommended Citation:
Sun J,Ou C,Wang C,et al. Silane-Functionalized N-Heterocyclic Carbene-Cobalt Complexes Containing a Five-Coordinate Silicon with a Covalent Co-Si Bond[J]. Organometallics,2015,34(8):1546-1551.
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