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Silane-Functionalized N-Heterocyclic Carbene-Cobalt Complexes Containing a Five-Coordinate Silicon with a Covalent Co-Si Bond
Alternative Title具有共价钴硅键的五配位硅的硅基官能团化的氮杂环卡宾钴配合物
Sun J(孙键)1; Ou C(欧翀)1; Wang C(王超)1; UCHIYAMA MASANOBU1; Deng L(邓亮)1
2015
Source PublicationOrganometallics
Volume34Issue:8Pages:1546-1551
AbstractNovel cobalt complexes featuring five-coordinate silicon centers with a covalent CoSi bond, i.e., [(SiN2C)Co(OPy)] complexes (SiN2C = tetradentate silane-anchored bis(pyridine)-N-heterocyclic carbene (NHC) ligand, OPy = 2-pyridonato), were prepared by reaction of bidentate hydrosilyl-NHC-supported cobalt(II) complexes with 2-pyridone and characterized by H-1, C-13, and Si-29 NMR, single-crystal X-ray diffraction, and elemental analyses. Theoretical calculations support a covalent nature of the CoSi interaction, in contrast to the metal -> Si dative bonds in metallasilatranes.
Subtype论文
Subject Area金属有机化学
DOI10.1021/acs.organomet.5b00114
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000353668700015
Citation statistics
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39598
Collection金属有机化学国家重点实验室
Corresponding AuthorWang C(王超); Deng L(邓亮)
Affiliation1.中科院上海有机化学研究所, 金属有机化学国家重点实验室
2.日本理化学研究所
3.日本东京大学
Recommended Citation
GB/T 7714
Sun J,Ou C,Wang C,et al. Silane-Functionalized N-Heterocyclic Carbene-Cobalt Complexes Containing a Five-Coordinate Silicon with a Covalent Co-Si Bond[J]. Organometallics,2015,34(8):1546-1551.
APA 孙键,欧翀,王超,UCHIYAMA MASANOBU,&邓亮.(2015).Silane-Functionalized N-Heterocyclic Carbene-Cobalt Complexes Containing a Five-Coordinate Silicon with a Covalent Co-Si Bond.Organometallics,34(8),1546-1551.
MLA 孙键,et al."Silane-Functionalized N-Heterocyclic Carbene-Cobalt Complexes Containing a Five-Coordinate Silicon with a Covalent Co-Si Bond".Organometallics 34.8(2015):1546-1551.
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