Silane-Functionalized N-Heterocyclic Carbene-Cobalt Complexes Containing a Five-Coordinate Silicon with a Covalent Co-Si Bond

doi:10.1021/acs.organomet.5b00114

	Silane-Functionalized N-Heterocyclic Carbene-Cobalt Complexes Containing a Five-Coordinate Silicon with a Covalent Co-Si Bond
其他题名	具有共价钴硅键的五配位硅的硅基官能团化的氮杂环卡宾钴配合物
	Sun J(孙键)1; Ou C(欧翀)1; Wang C(王超)1; UCHIYAMA MASANOBU 1; Deng L(邓亮)1
	2015
发表期刊	Organometallics
卷号	34 期号:8 页码:1546-1551
摘要	Novel cobalt complexes featuring five-coordinate silicon centers with a covalent CoSi bond, i.e., [(SiN2C)Co(OPy)] complexes (SiN2C = tetradentate silane-anchored bis(pyridine)-N-heterocyclic carbene (NHC) ligand, OPy = 2-pyridonato), were prepared by reaction of bidentate hydrosilyl-NHC-supported cobalt(II) complexes with 2-pyridone and characterized by H-1, C-13, and Si-29 NMR, single-crystal X-ray diffraction, and elemental analyses. Theoretical calculations support a covalent nature of the CoSi interaction, in contrast to the metal -> Si dative bonds in metallasilatranes.
文章类型	论文
学科领域	金属有机化学
DOI	10.1021/acs.organomet.5b00114
URL	查看原文
收录类别	SCI
语种	英语
WOS记录号	WOS:000353668700015
引用统计	被引频次：12[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.sioc.ac.cn/handle/331003/39598
专题	金属有机化学国家重点实验室
通讯作者	Wang C(王超); Deng L(邓亮)
作者单位	1.中科院上海有机化学研究所, 金属有机化学国家重点实验室 2.日本理化学研究所 3.日本东京大学
推荐引用方式 GB/T 7714	Sun J,Ou C,Wang C,et al. Silane-Functionalized N-Heterocyclic Carbene-Cobalt Complexes Containing a Five-Coordinate Silicon with a Covalent Co-Si Bond[J]. Organometallics,2015,34(8):1546-1551.
APA	孙键,欧翀,王超,UCHIYAMA MASANOBU,&邓亮.(2015).Silane-Functionalized N-Heterocyclic Carbene-Cobalt Complexes Containing a Five-Coordinate Silicon with a Covalent Co-Si Bond.Organometallics,34(8),1546-1551.
MLA	孙键,et al."Silane-Functionalized N-Heterocyclic Carbene-Cobalt Complexes Containing a Five-Coordinate Silicon with a Covalent Co-Si Bond".Organometallics 34.8(2015):1546-1551.

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