| Silane-Functionalized N-Heterocyclic Carbene-Cobalt Complexes Containing a Five-Coordinate Silicon with a Covalent Co-Si Bond | |
| Alternative Title | 具有共价钴硅键的五配位硅的硅基官能团化的氮杂环卡宾钴配合物 |
| Sun J(孙键)1; Ou C(欧翀)1; Wang C(王超)1; UCHIYAMA MASANOBU1; Deng L(邓亮)1 | |
| 2015 | |
| Source Publication | Organometallics
 |
| Volume | 34Issue:8Pages:1546-1551 |
| Abstract | Novel cobalt complexes featuring five-coordinate silicon centers with a covalent CoSi bond, i.e., [(SiN2C)Co(OPy)] complexes (SiN2C = tetradentate silane-anchored bis(pyridine)-N-heterocyclic carbene (NHC) ligand, OPy = 2-pyridonato), were prepared by reaction of bidentate hydrosilyl-NHC-supported cobalt(II) complexes with 2-pyridone and characterized by H-1, C-13, and Si-29 NMR, single-crystal X-ray diffraction, and elemental analyses. Theoretical calculations support a covalent nature of the CoSi interaction, in contrast to the metal -> Si dative bonds in metallasilatranes. |
| Subtype | 论文 |
| Subject Area | 金属有机化学 |
| DOI | 10.1021/acs.organomet.5b00114 |
| URL | 查看原文 |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000353668700015 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sioc.ac.cn/handle/331003/39598 |
| Collection | 金属有机化学国家重点实验室 |
| Corresponding Author | Wang C(王超); Deng L(邓亮) |
| Affiliation | 1.中科院上海有机化学研究所, 金属有机化学国家重点实验室 2.日本理化学研究所 3.日本东京大学 |
| Recommended Citation GB/T 7714 | Sun J,Ou C,Wang C,et al. Silane-Functionalized N-Heterocyclic Carbene-Cobalt Complexes Containing a Five-Coordinate Silicon with a Covalent Co-Si Bond[J]. Organometallics,2015,34(8):1546-1551. |
| APA | 孙键,欧翀,王超,UCHIYAMA MASANOBU,&邓亮.(2015).Silane-Functionalized N-Heterocyclic Carbene-Cobalt Complexes Containing a Five-Coordinate Silicon with a Covalent Co-Si Bond.Organometallics,34(8),1546-1551. |
| MLA | 孙键,et al."Silane-Functionalized N-Heterocyclic Carbene-Cobalt Complexes Containing a Five-Coordinate Silicon with a Covalent Co-Si Bond".Organometallics 34.8(2015):1546-1551. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 2015238.pdf（1158KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | Application Full Text | |
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment