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Highly Efficient Ruthenium-Catalyzed N-Formylation of Amines with H-2 and CO2
Alternative Title钌催化的用二氧化碳和氢气对胺的高效N-甲酰化反应
Zhang L(张磊); Han ZB(韩召斌); Zhao XY(赵骁宇); Wang Z(王正); Ding KL(丁奎岭)
2015
Source PublicationAngew. Chem.-Int. Edit.
Volume54Issue:21Pages:6186-6189
AbstractA highly efficient catalyst system based on ruthenium-pincer-type complexes has been discovered for N-formylation of various amines with CO2 and H-2, thus affording the corresponding formamides with excellent productivity (turnover numbers of up to 1940000 in a single batch) and selectivity. Using a simple catalyst recycling protocol, the catalyst was reused for 12 runs in N,N-dimethylformamide production without significant loss of activity, thus demonstrating the potential for practical utilization of this cost-effective process. A one-pot two-step procedure for hydrogenation of CO2 to methanol via the intermediacy of formamide formation has also been developed.
Subtype论文
Subject Area金属有机化学
DOI10.1002/anie.201500939
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000354260000011
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39596
Collection金属有机化学国家重点实验室
Corresponding AuthorDing KL(丁奎岭)
Affiliation中科院上海有机化学研究所, 金属有机化学国家重点实验室
Recommended Citation
GB/T 7714
Zhang L,Han ZB,Zhao XY,et al. Highly Efficient Ruthenium-Catalyzed N-Formylation of Amines with H-2 and CO2[J]. Angew. Chem.-Int. Edit.,2015,54(21):6186-6189.
APA 张磊,韩召斌,赵骁宇,王正,&丁奎岭.(2015).Highly Efficient Ruthenium-Catalyzed N-Formylation of Amines with H-2 and CO2.Angew. Chem.-Int. Edit.,54(21),6186-6189.
MLA 张磊,et al."Highly Efficient Ruthenium-Catalyzed N-Formylation of Amines with H-2 and CO2".Angew. Chem.-Int. Edit. 54.21(2015):6186-6189.
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