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学科主题: 金属有机化学
题名: Highly Efficient Ruthenium-Catalyzed N-Formylation of Amines with H-2 and CO2
其他题名: 钌催化的用二氧化碳和氢气对胺的高效N-甲酰化反应
作者: Zhang L(张磊); Han ZB(韩召斌); Zhao XY(赵骁宇); Wang Z(王正); Ding KL(丁奎岭)
通讯作者: 丁奎岭
刊名: Angew. Chem.-Int. Edit.
发表日期: 2015
DOI: 10.1002/anie.201500939
卷: 54, 期:21, 页:6186-6189
收录类别: SCI
文章类型: 论文
英文摘要: A highly efficient catalyst system based on ruthenium-pincer-type complexes has been discovered for N-formylation of various amines with CO2 and H-2, thus affording the corresponding formamides with excellent productivity (turnover numbers of up to 1940000 in a single batch) and selectivity. Using a simple catalyst recycling protocol, the catalyst was reused for 12 runs in N,N-dimethylformamide production without significant loss of activity, thus demonstrating the potential for practical utilization of this cost-effective process. A one-pot two-step procedure for hydrogenation of CO2 to methanol via the intermediacy of formamide formation has also been developed.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000354260000011
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39596
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 金属有机化学国家重点实验室

Recommended Citation:
Zhang L,Han ZB,Zhao XY,et al. Highly Efficient Ruthenium-Catalyzed N-Formylation of Amines with H-2 and CO2[J]. Angew. Chem.-Int. Edit.,2015,54(21):6186-6189.
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