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学科主题: 金属有机化学
题名: Palladium-catalyzed highly efficient synthesis of functionalized indolizines via cross-coupling/cycloisomerization cascade
其他题名: 钯催化的交叉偶联/环异构化串联反应: 官能团化中氮茚的高效合成
作者: Zhang LW(张良伟)1; Li XD(李向东)1; Liu YH(刘元红)1; Zhang DY(张大永)1
通讯作者: 刘元红 ; 张大永
刊名: Chem. Commun.
发表日期: 2015
DOI: 10.1039/c5cc01151e
卷: 51, 期:30, 页:6633-6636
收录类别: SCI
文章类型: 论文
英文摘要: An efficient Pd-catalyzed cross-coupling/cycloisomerization of 3-(2-pyridyl) propargyl carbonates with organoboronic acids has been developed, which provides a straightforward route for the synthesis of 1,3-disubstituted indolizines with a wide variety of substituents. The mechanistic study indicates that the reaction proceeds via formation of an allenyl pyridine intermediate through palladium-catalyzed coupling reaction followed by cyclization.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000352269000041
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39594
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 1.中国药科大学
2.中科院上海有机化学研究所, 金属有机化学国家重点实验室

Recommended Citation:
Zhang LW,Li XD,Liu YH,et al. Palladium-catalyzed highly efficient synthesis of functionalized indolizines via cross-coupling/cycloisomerization cascade[J]. Chem. Commun.,2015,51(30):6633-6636.
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