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学科主题: 金属有机化学
题名: 氧化型导向基诱导的C-H键官能团化
其他题名: C-H Functionalization Induced by the Oxidizing Directing Group
作者: 胡志勇1; 童晓峰1; 刘桂霞1
通讯作者: 童晓峰 ; 刘桂霞
刊名: 有机化学
发表日期: 2015
DOI: 10.6023/cjoc201412050
卷: 35, 期:3, 页:539-555
收录类别: SCI
文章类型: 论文
英文摘要: Transition-metal catalyzed C-H functionalization is a straightforward and efficient way to construct C-C and C-X bonds. However, these transformations usually require stioichiometric or excess amount of external oxidants to oxidize low valent metal and regenerate the active catalytic species. The use of the oxidizing directing group, which contains some special group acting as the internal oxidant, can avoid the troubles arousing from the external oxidants and make the reaction process more simple and efficient. Recently, increasing number of novel oxidizing directing groups have been designed and diverse kinds of reactions have been developed. This approach can be used to synthesize kinds of heterocyles or highly functionalized products under external oxidant free conditions.
语种: 中文
相关网址: 查看原文
WOS记录号: WOS:000353081600004
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39591
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 1.华东理工大学
2.中科院上海有机化学研究所, 金属有机化学国家重点实验室

Recommended Citation:
胡志勇,童晓峰,刘桂霞. 氧化型导向基诱导的C-H键官能团化[J]. 有机化学,2015,35(3):539-555.
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