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Harmony of CdI2 with CuBr for the one-pot synthesis of optically active alpha-allenols
Alternative TitleCdI2和CuBr共催化的一锅法合成光学活性的α-联烯醇的方法
Zhang JS(张加生)1; Ye JT(叶俊涛)1; Ma SM(麻生明)1
2015
Source PublicationOrg. Biomol. Chem.
Volume13Issue:13Pages:4080-4089
AbstractA highly efficient one-pot synthesis of chiral alpha-allenols from propargylic alcohols, aldehydes and pyrrolidine induced by CuBr and (R,R-a)-N-PINAP or (R,S-a)-N-PINAP and CdI2 has been developed. Both the yields and enantioselectivities of the allenols of this one-pot procedure are practical. Comparison with ZnI2 control experiments revealed that CdI2 can convert propargylic amine to allene in the presence of CuBr efficiently.
Subtype论文
Subject Area金属有机化学
DOI10.1039/c4ob02673j
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000351597700028
Citation statistics
Cited Times:9[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39589
Collection金属有机化学国家重点实验室
Corresponding AuthorMa SM(麻生明)
Affiliation1.中科院上海有机化学研究所, 金属有机化学国家重点实验室
2.复旦大学
Recommended Citation
GB/T 7714
Zhang JS,Ye JT,Ma SM. Harmony of CdI2 with CuBr for the one-pot synthesis of optically active alpha-allenols[J]. Org. Biomol. Chem.,2015,13(13):4080-4089.
APA 张加生,叶俊涛,&麻生明.(2015).Harmony of CdI2 with CuBr for the one-pot synthesis of optically active alpha-allenols.Org. Biomol. Chem.,13(13),4080-4089.
MLA 张加生,et al."Harmony of CdI2 with CuBr for the one-pot synthesis of optically active alpha-allenols".Org. Biomol. Chem. 13.13(2015):4080-4089.
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