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学科主题: 金属有机化学
题名: Harmony of CdI2 with CuBr for the one-pot synthesis of optically active alpha-allenols
其他题名: CdI2和CuBr共催化的一锅法合成光学活性的α-联烯醇的方法
作者: Zhang JS(张加生)1; Ye JT(叶俊涛)1; Ma SM(麻生明)1
通讯作者: 麻生明
刊名: Org. Biomol. Chem.
发表日期: 2015
DOI: 10.1039/c4ob02673j
卷: 13, 期:13, 页:4080-4089
收录类别: SCI
文章类型: 论文
英文摘要: A highly efficient one-pot synthesis of chiral alpha-allenols from propargylic alcohols, aldehydes and pyrrolidine induced by CuBr and (R,R-a)-N-PINAP or (R,S-a)-N-PINAP and CdI2 has been developed. Both the yields and enantioselectivities of the allenols of this one-pot procedure are practical. Comparison with ZnI2 control experiments revealed that CdI2 can convert propargylic amine to allene in the presence of CuBr efficiently.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000351597700028
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39589
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所, 金属有机化学国家重点实验室
2.复旦大学

Recommended Citation:
Zhang JS,Ye JT,Ma SM. Harmony of CdI2 with CuBr for the one-pot synthesis of optically active alpha-allenols[J]. Org. Biomol. Chem.,2015,13(13):4080-4089.
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