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学科主题: 金属有机化学
题名: Cp2TiCl2-catalyzed cis-hydroalumination of propargylic amines with Red-Al: stereoselective synthesis of Z-configured allylic amines
其他题名: 二氯二茂钛催化的丙炔胺与红鋁的顺式鋁氢化反应:高立体选择性合成顺式烯丙基胺衍生物
作者: Sun RH(孙仁红); Liu J(刘俊); Yang S(杨爽); Chen M(陈铭); Sun N(孙宁); Chen HY(陈好益); Jie X(解鑫); You X(尤旭); Li S(李石); Liu YH(刘元红)
通讯作者: 刘元红
刊名: Chem. Commun.
发表日期: 2015
DOI: 10.1039/c5cc00950b
卷: 51, 期:29, 页:6426-6433
收录类别: SCI
文章类型: 论文
英文摘要: A titanium-catalyzed cis-hydroalumination of propargylic amines with Red-Al is described, which provides an efficient way to produce Z-configured allylic amines in good to excellent yields with high stereoselectivity and good regioselectivity. The hydride-bridged Al/Ti bimetallic species may act as a real catalyst in this reaction.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000351843500041
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39587
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 金属有机化学国家重点实验室

Recommended Citation:
Sun RH,Liu J,Yang S,et al. Cp2TiCl2-catalyzed cis-hydroalumination of propargylic amines with Red-Al: stereoselective synthesis of Z-configured allylic amines[J]. Chem. Commun.,2015,51(29):6426-6433.
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