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Palladium-Catalyzed Intramolecular Aminoacetoxylation of Unactivated Alkenes with Hydrogen Peroxide as Oxidant
Alternative Title钯催化非活性烯烃的分子内胺乙酰基化反应
Zhu HT(朱海涛); Chen PH(陈品红); Liu GS(刘国生)
2015
Source PublicationOrg. Lett.
Volume17Issue:6Pages:1485-1488
AbstractA palladium-catalyzed intramolecular aminoacetoxylation of unactivated alkenes was developed in which H2O2 was used as the sole oxidant. A variety of 3-acetoxylated piperidines were obtained in good yields with good to excellent regio- and diastereoselectivities. Mechanistic study revealed that the addition of di(2-pyridyl) ketone (dpk) ligand was crucial to promote the oxidative cleavage of the C-Pd(II) bond by H2O2 to give the C-OAc bond.
Subtype论文
Subject Area金属有机化学
DOI10.1021/acs.orglett.5b00373
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000351558100035
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39585
Collection金属有机化学国家重点实验室
Corresponding AuthorLiu GS(刘国生)
Affiliation中科院上海有机化学研究所, 金属有机化学国家重点实验室
Recommended Citation
GB/T 7714
Zhu HT,Chen PH,Liu GS. Palladium-Catalyzed Intramolecular Aminoacetoxylation of Unactivated Alkenes with Hydrogen Peroxide as Oxidant[J]. Org. Lett.,2015,17(6):1485-1488.
APA 朱海涛,陈品红,&刘国生.(2015).Palladium-Catalyzed Intramolecular Aminoacetoxylation of Unactivated Alkenes with Hydrogen Peroxide as Oxidant.Org. Lett.,17(6),1485-1488.
MLA 朱海涛,et al."Palladium-Catalyzed Intramolecular Aminoacetoxylation of Unactivated Alkenes with Hydrogen Peroxide as Oxidant".Org. Lett. 17.6(2015):1485-1488.
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