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Rhodium-catalyzed C-H functionalization-based approach to eight-membered lactams
Alternative Title铑催化的通过C-H键活化合成八元内酰胺的方法
Wu SZ(吴尚泽)1; Ceng R(曾荣)1; Fu CL(傅春玲)1; Yu YH(余亦华)1; Zhang X(张雪)1; Ma SM(麻生明)1
2015
Source PublicationChem. Sci.
Volume6Issue:4Pages:2275-2285
AbstractA Rh(III) catalyzed formal [4 + 2 + 2] cyclization of N-pivaloyloxybenzamides 1 with 1,6-allene-enes 2 by C-H functionalization is reported. The reactions occur at room temperature and are compatible with air and moisture with a tolerance of many synthetically useful functional groups. The follow-up modifications of the products have been demonstrated. After careful mechanistic studies and DFT calculation, a reaction mechanism was proposed.
Subtype论文
Subject Area金属有机化学
DOI10.1039/c5sc00092k
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000351412800016
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39584
Collection金属有机化学国家重点实验室
Corresponding AuthorZhang X(张雪); Ma SM(麻生明)
Affiliation1.浙江大学
2.中科院上海有机化学研究所, 金属有机化学国家重点实验室
Recommended Citation
GB/T 7714
Wu SZ,Ceng R,Fu CL,et al. Rhodium-catalyzed C-H functionalization-based approach to eight-membered lactams[J]. Chem. Sci.,2015,6(4):2275-2285.
APA 吴尚泽,曾荣,傅春玲,余亦华,张雪,&麻生明.(2015).Rhodium-catalyzed C-H functionalization-based approach to eight-membered lactams.Chem. Sci.,6(4),2275-2285.
MLA 吴尚泽,et al."Rhodium-catalyzed C-H functionalization-based approach to eight-membered lactams".Chem. Sci. 6.4(2015):2275-2285.
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