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Rh-II-Catalyzed [3+2] Cycloaddition of 2H-Azirines with N-Sulfonyl-1,2,3-Triazoles
Alternative Title铑(II)催化的氮杂三元环和三氮唑的[3+2]环加成反应
Zhao YZ(赵允州); Yang HB(杨海斌); Tang XY(唐翔鹰); Shi M(施敏)
Source PublicationChem.-Eur. J.
AbstractRh-II-catalyzed intermolecular [3+2] cycloaddition of 2H-azirines with N-sulfonyl-1,2,3-triazoles is disclosed, in which a series of fully functionalized pyrroles is produced via rhodium azavinyl carbene intermediates. A distinct feature of this reaction is that the azavinyl carbene serves as a [2C] equivalent, instead of as [1C] or aza-[3C] synthons, which have been reported previously in cyclopropanations and [3+n] cycloadditions. Moreover, this methodology has also been successfully applied in the total synthesis of URB447 as well as the formal synthesis of Atorvastatin (Lipitor).
Subject Area金属有机化学
Indexed BySCI
WOS IDWOS:000350116200010
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Document Type期刊论文
Corresponding AuthorTang XY(唐翔鹰); Shi M(施敏)
Affiliation中科院上海有机化学研究所, 金属有机化学国家重点实验室
Recommended Citation
GB/T 7714
Zhao YZ,Yang HB,Tang XY,et al. Rh-II-Catalyzed [3+2] Cycloaddition of 2H-Azirines with N-Sulfonyl-1,2,3-Triazoles[J]. Chem.-Eur. J.,2015,21(9):3562-3566.
APA 赵允州,杨海斌,唐翔鹰,&施敏.(2015).Rh-II-Catalyzed [3+2] Cycloaddition of 2H-Azirines with N-Sulfonyl-1,2,3-Triazoles.Chem.-Eur. J.,21(9),3562-3566.
MLA 赵允州,et al."Rh-II-Catalyzed [3+2] Cycloaddition of 2H-Azirines with N-Sulfonyl-1,2,3-Triazoles".Chem.-Eur. J. 21.9(2015):3562-3566.
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