中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 金属有机化学国家重点实验室  > 期刊论文
学科主题: 金属有机化学
题名: Highly Selective Pd-Catalyzed Intermolecular Fluorosulfonylation of Styrenes
其他题名: 钯催化苯乙烯的分子间高选择性氟硫化反应
作者: Yuan ZL(袁浙梁); Wang HY(王昊阳); Mu X(慕欣); Guo YL(郭寅龙); Liu GS(刘国生)
通讯作者: 刘国生
刊名: J. Am. Chem. Soc.
发表日期: 2015
DOI: 10.1021/ja5131676
卷: 137, 期:7, 页:2468-2471
收录类别: SCI
文章类型: 论文
英文摘要: A novel Pd-catalyzed intermolecular regio- and diastereoselective fluorosulfonylation of styrenes has been developed under mild conditions. This reaction exhibits a wide range of functional-group tolerance in styrenes and arylsulfinic acids to afford various beta-fluoro sulfones. Preliminary mechanistic study reveals an unusual mechanism, in which a high-valent (L2PdF)-F-III species side-selectively reacts with a benzylic carbon radical to deliver a C-F bond. This pathway is distinct from a previously reported radical fluorination reaction.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000350192700015
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39578
Appears in Collections:金属有机化学国家重点实验室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2015130.pdf(1138KB)期刊论文作者接受稿开放获取View Download

作者单位: 中科院上海有机化学研究所, 金属有机化学国家重点实验室

Recommended Citation:
Yuan ZL,Wang HY,Mu X,et al. Highly Selective Pd-Catalyzed Intermolecular Fluorosulfonylation of Styrenes[J]. J. Am. Chem. Soc.,2015,137(7):2468-2471.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[袁浙梁]'s Articles
[王昊阳]'s Articles
[慕欣]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[袁浙梁]‘s Articles
[王昊阳]‘s Articles
[慕欣]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2015130.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace