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学科主题: 金属有机化学
题名: An Enantioselective Synthesis of (R)-5,6-Octadecadienoic Acid
其他题名: 对映选择性合成(R)-5,6-十八碳二烯酸
作者: Yu Q(俞琼)1; Ma SM(麻生明)1
通讯作者: 麻生明
刊名: Eur. J. Org. Chem.
发表日期: 2015
DOI: 10.1002/ejoc.201403588
期: 7, 页:1596-1601
收录类别: SCI
文章类型: 论文
英文摘要: A convenient, scalable, and highly enantioselective total synthesis of (R)-5,6-octadecadienoic acid was developed by using the recently established ATA (allenylation of terminal alkynes) reaction of TBS-protected (TBS = tert-butyldimethylsilyl) propargyl alcohol with n-dodecanal in the pres-ence of (R)-alpha,alpha-diphenylprolinol as the chiral source. The axial chirality of the allene unit withstood the many common organic transformations that were needed to achieve the total synthesis with a high ee (enantiomeric excess) value.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000349973500027
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39577
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 1.华东师范大学
2.中科院上海有机化学研究所, 金属有机化学国家重点实验室

Recommended Citation:
Yu Q,Ma SM. An Enantioselective Synthesis of (R)-5,6-Octadecadienoic Acid[J]. Eur. J. Org. Chem.,2015(7):1596-1601.
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