SIOC OpenIR  > 金属有机化学国家重点实验室
An Enantioselective Synthesis of (R)-5,6-Octadecadienoic Acid
Alternative Title对映选择性合成(R)-5,6-十八碳二烯酸
Yu Q(俞琼)1; Ma SM(麻生明)1
2015
Source PublicationEur. J. Org. Chem.
Issue7Pages:1596-1601
AbstractA convenient, scalable, and highly enantioselective total synthesis of (R)-5,6-octadecadienoic acid was developed by using the recently established ATA (allenylation of terminal alkynes) reaction of TBS-protected (TBS = tert-butyldimethylsilyl) propargyl alcohol with n-dodecanal in the pres-ence of (R)-alpha,alpha-diphenylprolinol as the chiral source. The axial chirality of the allene unit withstood the many common organic transformations that were needed to achieve the total synthesis with a high ee (enantiomeric excess) value.
Subtype论文
Subject Area金属有机化学
DOI10.1002/ejoc.201403588
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000349973500027
Citation statistics
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39577
Collection金属有机化学国家重点实验室
Corresponding AuthorMa SM(麻生明)
Affiliation1.华东师范大学
2.中科院上海有机化学研究所, 金属有机化学国家重点实验室
Recommended Citation
GB/T 7714
Yu Q,Ma SM. An Enantioselective Synthesis of (R)-5,6-Octadecadienoic Acid[J]. Eur. J. Org. Chem.,2015(7):1596-1601.
APA 俞琼,&麻生明.(2015).An Enantioselective Synthesis of (R)-5,6-Octadecadienoic Acid.Eur. J. Org. Chem.(7),1596-1601.
MLA 俞琼,et al."An Enantioselective Synthesis of (R)-5,6-Octadecadienoic Acid".Eur. J. Org. Chem. .7(2015):1596-1601.
Files in This Item:
File Name/Size DocType Version Access License
2015127.pdf(643KB)期刊论文作者接受稿开放获取CC BY-NC-SAApplication Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[俞琼]'s Articles
[麻生明]'s Articles
Baidu academic
Similar articles in Baidu academic
[俞琼]'s Articles
[麻生明]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[俞琼]'s Articles
[麻生明]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.