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An Enantioselective Synthesis of (R)-5,6-Octadecadienoic Acid
Alternative Title对映选择性合成(R)-5,6-十八碳二烯酸
Yu Q(俞琼)1; Ma SM(麻生明)1
Source PublicationEur. J. Org. Chem.
AbstractA convenient, scalable, and highly enantioselective total synthesis of (R)-5,6-octadecadienoic acid was developed by using the recently established ATA (allenylation of terminal alkynes) reaction of TBS-protected (TBS = tert-butyldimethylsilyl) propargyl alcohol with n-dodecanal in the pres-ence of (R)-alpha,alpha-diphenylprolinol as the chiral source. The axial chirality of the allene unit withstood the many common organic transformations that were needed to achieve the total synthesis with a high ee (enantiomeric excess) value.
Subject Area金属有机化学
Indexed BySCI
WOS IDWOS:000349973500027
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Document Type期刊论文
Corresponding AuthorMa SM(麻生明)
2.中科院上海有机化学研究所, 金属有机化学国家重点实验室
Recommended Citation
GB/T 7714
Yu Q,Ma SM. An Enantioselective Synthesis of (R)-5,6-Octadecadienoic Acid[J]. Eur. J. Org. Chem.,2015(7):1596-1601.
APA 俞琼,&麻生明.(2015).An Enantioselective Synthesis of (R)-5,6-Octadecadienoic Acid.Eur. J. Org. Chem.(7),1596-1601.
MLA 俞琼,et al."An Enantioselective Synthesis of (R)-5,6-Octadecadienoic Acid".Eur. J. Org. Chem. .7(2015):1596-1601.
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