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学科主题: 金属有机化学
题名: Enantioselective Palladium-Catalyzed Dearomative Cyclization for the Efficient Synthesis of Terpenes and Steroids
其他题名: 对映性选择性去芳构环化高效合成萜类和甾体
作者: Du K(杜康); Guo P(郭盼); Chen Y(陈远); Cao Z(曹振); Tang WJ(汤文军)
通讯作者: 汤文军
刊名: Angew. Chem.-Int. Edit.
发表日期: 2015
DOI: 10.1002/anie.201411817
卷: 54, 期:10, 页:3033-3037
收录类别: SCI
文章类型: 论文
英文摘要: A novel enantioselective palladium-catalyzed dearomative cyclization has been developed for the efficient construction of a series of chiral phenanthrenone derivatives bearing an all-carbon quaternary center. The effectiveness of this method in the synthesis of terpenes and steroids was demonstrated by a highly efficient synthesis of a kaurene intermediate, the facile construction of the skeleton of the anabolic steroid boldenone, and the enantioselective total synthesis of the antimicrobial diterpene natural product (-)-totaradiol.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000350302300027
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39576
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 生命有机化学国家重点实验室

Recommended Citation:
Du K,Guo P,Chen Y,et al. Enantioselective Palladium-Catalyzed Dearomative Cyclization for the Efficient Synthesis of Terpenes and Steroids[J]. Angew. Chem.-Int. Edit.,2015,54(10):3033-3037.
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