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Cadmium Iodide Mediated Allenylation of Terminal Alkynes for the Synthesis of Methyl-Substituted Allenes
Alternative Title碘化镉促进的从末端炔出发合成甲基取代的联烯的反应
Tang XJ(汤鑫军)1; Han YL(韩玉林)1; Ma SM(麻生明)1
2015
Source PublicationOrg. Lett.
Volume17Issue:5Pages:1176-1179
AbstractA cadmium iodide mediated tandem reaction involving amine and two molecules of terminal alkynes for the synthesis of trisubstituted allenes has been developed. By applying this protocol, methyl-substituted allenes may be obtained easily from two molecules of terminal alkynes and pyrrolidine via methyl ketoniminium and propargylic amine formation, 1,5-hydride transfer and beta-elimination.
Subtype论文
Subject Area金属有机化学
DOI10.1021/acs.orglett.5b00105
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000350841300030
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39574
Collection金属有机化学国家重点实验室
Corresponding AuthorMa SM(麻生明)
Affiliation1.中科院上海有机化学研究所, 金属有机化学国家重点实验室
2.复旦大学
Recommended Citation
GB/T 7714
Tang XJ,Han YL,Ma SM. Cadmium Iodide Mediated Allenylation of Terminal Alkynes for the Synthesis of Methyl-Substituted Allenes[J]. Org. Lett.,2015,17(5):1176-1179.
APA 汤鑫军,韩玉林,&麻生明.(2015).Cadmium Iodide Mediated Allenylation of Terminal Alkynes for the Synthesis of Methyl-Substituted Allenes.Org. Lett.,17(5),1176-1179.
MLA 汤鑫军,et al."Cadmium Iodide Mediated Allenylation of Terminal Alkynes for the Synthesis of Methyl-Substituted Allenes".Org. Lett. 17.5(2015):1176-1179.
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