| Cadmium Iodide Mediated Allenylation of Terminal Alkynes for the Synthesis of Methyl-Substituted Allenes | |
| Alternative Title | 碘化镉促进的从末端炔出发合成甲基取代的联烯的反应 |
| Tang XJ(汤鑫军)1; Han YL(韩玉林)1; Ma SM(麻生明)1 | |
| 2015 | |
| Source Publication | Org. Lett.
 |
| Volume | 17Issue:5Pages:1176-1179 |
| Abstract | A cadmium iodide mediated tandem reaction involving amine and two molecules of terminal alkynes for the synthesis of trisubstituted allenes has been developed. By applying this protocol, methyl-substituted allenes may be obtained easily from two molecules of terminal alkynes and pyrrolidine via methyl ketoniminium and propargylic amine formation, 1,5-hydride transfer and beta-elimination. |
| Subtype | 论文 |
| Subject Area | 金属有机化学 |
| DOI | 10.1021/acs.orglett.5b00105 |
| URL | 查看原文 |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000350841300030 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sioc.ac.cn/handle/331003/39574 |
| Collection | 金属有机化学国家重点实验室 |
| Corresponding Author | Ma SM(麻生明) |
| Affiliation | 1.中科院上海有机化学研究所, 金属有机化学国家重点实验室 2.复旦大学 |
| Recommended Citation GB/T 7714 | Tang XJ,Han YL,Ma SM. Cadmium Iodide Mediated Allenylation of Terminal Alkynes for the Synthesis of Methyl-Substituted Allenes[J]. Org. Lett.,2015,17(5):1176-1179. |
| APA | 汤鑫军,韩玉林,&麻生明.(2015).Cadmium Iodide Mediated Allenylation of Terminal Alkynes for the Synthesis of Methyl-Substituted Allenes.Org. Lett.,17(5),1176-1179. |
| MLA | 汤鑫军,et al."Cadmium Iodide Mediated Allenylation of Terminal Alkynes for the Synthesis of Methyl-Substituted Allenes".Org. Lett. 17.5(2015):1176-1179. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 2015116.pdf（333KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | Application Full Text | |
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