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学科主题: 金属有机化学
题名: Enantioselective synthesis of 4-substituted tetrahydroisoquinolines via palladium-catalyzed intramolecular Friedel-Crafts type allylic alkylation of phenols
其他题名: 钯催化苯酚的分子内Friedel-Crafts型烯丙基烷基化反应不对称合成4-取代四氢异喹啉化合物
作者: Zhao ZL(赵正乐)1; Xu QL(许庆龙)1; Gu Q(顾庆)1; Wu XY(伍新燕)1; You SL(游书力)1
通讯作者: 伍新燕 ; 游书力
刊名: Org. Biomol. Chem.
发表日期: 2015
DOI: 10.1039/c4ob02574a
卷: 13, 期:10, 页:3086-3092
收录类别: SCI
文章类型: 论文
英文摘要: Palladium-catalyzed asymmetric intramolecular Friedel-Crafts type allylic alkylation reaction of phenols was developed under mild conditions. In the presence of Pd-2(dba)(3) with (1R,2R)-DACH-phenyl Trost ligand (L2) in toluene at 50 degrees C, the reaction provides various C4 substituted tetrahydroisoquinolines with moderate to excellent yields, regioselectivity and enantioselectivity.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000350674400033
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39573
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 1.华东理工大学
2.中科院上海有机化学研究所, 金属有机化学国家重点实验室

Recommended Citation:
Zhao ZL,Xu QL,Gu Q,et al. Enantioselective synthesis of 4-substituted tetrahydroisoquinolines via palladium-catalyzed intramolecular Friedel-Crafts type allylic alkylation of phenols[J]. Org. Biomol. Chem.,2015,13(10):3086-3092.
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