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Enantioselective synthesis of 4-substituted tetrahydroisoquinolines via palladium-catalyzed intramolecular Friedel-Crafts type allylic alkylation of phenols
Alternative Title钯催化苯酚的分子内Friedel-Crafts型烯丙基烷基化反应不对称合成4-取代四氢异喹啉化合物
Zhao ZL(赵正乐)1; Xu QL(许庆龙)1; Gu Q(顾庆)1; Wu XY(伍新燕)1; You SL(游书力)1
2015
Source PublicationOrg. Biomol. Chem.
Volume13Issue:10Pages:3086-3092
AbstractPalladium-catalyzed asymmetric intramolecular Friedel-Crafts type allylic alkylation reaction of phenols was developed under mild conditions. In the presence of Pd-2(dba)(3) with (1R,2R)-DACH-phenyl Trost ligand (L2) in toluene at 50 degrees C, the reaction provides various C4 substituted tetrahydroisoquinolines with moderate to excellent yields, regioselectivity and enantioselectivity.
Subtype论文
Subject Area金属有机化学
DOI10.1039/c4ob02574a
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000350674400033
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39573
Collection金属有机化学国家重点实验室
Corresponding AuthorWu XY(伍新燕); You SL(游书力)
Affiliation1.华东理工大学
2.中科院上海有机化学研究所, 金属有机化学国家重点实验室
Recommended Citation
GB/T 7714
Zhao ZL,Xu QL,Gu Q,et al. Enantioselective synthesis of 4-substituted tetrahydroisoquinolines via palladium-catalyzed intramolecular Friedel-Crafts type allylic alkylation of phenols[J]. Org. Biomol. Chem.,2015,13(10):3086-3092.
APA 赵正乐,许庆龙,顾庆,伍新燕,&游书力.(2015).Enantioselective synthesis of 4-substituted tetrahydroisoquinolines via palladium-catalyzed intramolecular Friedel-Crafts type allylic alkylation of phenols.Org. Biomol. Chem.,13(10),3086-3092.
MLA 赵正乐,et al."Enantioselective synthesis of 4-substituted tetrahydroisoquinolines via palladium-catalyzed intramolecular Friedel-Crafts type allylic alkylation of phenols".Org. Biomol. Chem. 13.10(2015):3086-3092.
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