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Efficient Synthesis of Sterically Hindered Arenes Bearing Acyclic Secondary Alkyl Groups by Suzuki-Miyaura Cross-Couplings
其他题名利用Suzuki-Miyaura交叉偶联高效合成大位阻二级烷基芳烃
Li CX(李承喜); Chen TY(陈天宇); Li BW(李博文); Xiao GL(肖国兰); Tang WJ(汤文军)
2015
发表期刊Angew. Chem.-Int. Edit.
卷号54期号:12页码:3792-3796
摘要Bulky P,P=O ligands were designed to inhibit isomerization and reduction side reactions during the cross coupling between sterically hindered aryl halides and alkylboronic acids. Suzuki-Miyaura cross-couplings between di-ortho-substituted aryl bromides and acyclic secondary alkylboronic acids have been achieved with high yields. The method has also enabled the preparation of ortho-alkoxy di-ortho-substituted arenes bearing isopropyl groups in excellent yields. The utility of the synthetic method has been demonstrated in a late-stage modification of estrone and in the application to a new synthetic route toward gossypol.
文章类型论文
学科领域金属有机化学
DOI10.1002/anie.201411518
URL查看原文
收录类别SCI
语种英语
WOS记录号WOS:000351178300047
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文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/39572
专题金属有机化学国家重点实验室
通讯作者Tang WJ(汤文军)
作者单位中科院上海有机化学研究所, 生命有机化学国家重点实验室
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GB/T 7714
Li CX,Chen TY,Li BW,et al. Efficient Synthesis of Sterically Hindered Arenes Bearing Acyclic Secondary Alkyl Groups by Suzuki-Miyaura Cross-Couplings[J]. Angew. Chem.-Int. Edit.,2015,54(12):3792-3796.
APA 李承喜,陈天宇,李博文,肖国兰,&汤文军.(2015).Efficient Synthesis of Sterically Hindered Arenes Bearing Acyclic Secondary Alkyl Groups by Suzuki-Miyaura Cross-Couplings.Angew. Chem.-Int. Edit.,54(12),3792-3796.
MLA 李承喜,et al."Efficient Synthesis of Sterically Hindered Arenes Bearing Acyclic Secondary Alkyl Groups by Suzuki-Miyaura Cross-Couplings".Angew. Chem.-Int. Edit. 54.12(2015):3792-3796.
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