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学科主题: 金属有机化学
题名: Efficient Synthesis of Sterically Hindered Arenes Bearing Acyclic Secondary Alkyl Groups by Suzuki-Miyaura Cross-Couplings
其他题名: 利用Suzuki-Miyaura交叉偶联高效合成大位阻二级烷基芳烃
作者: Li CX(李承喜); Chen TY(陈天宇); Li BW(李博文); Xiao GL(肖国兰); Tang WJ(汤文军)
通讯作者: 汤文军
刊名: Angew. Chem.-Int. Edit.
发表日期: 2015
DOI: 10.1002/anie.201411518
卷: 54, 期:12, 页:3792-3796
收录类别: SCI
文章类型: 论文
英文摘要: Bulky P,P=O ligands were designed to inhibit isomerization and reduction side reactions during the cross coupling between sterically hindered aryl halides and alkylboronic acids. Suzuki-Miyaura cross-couplings between di-ortho-substituted aryl bromides and acyclic secondary alkylboronic acids have been achieved with high yields. The method has also enabled the preparation of ortho-alkoxy di-ortho-substituted arenes bearing isopropyl groups in excellent yields. The utility of the synthetic method has been demonstrated in a late-stage modification of estrone and in the application to a new synthetic route toward gossypol.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000351178300047
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39572
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 生命有机化学国家重点实验室

Recommended Citation:
Li CX,Chen TY,Li BW,et al. Efficient Synthesis of Sterically Hindered Arenes Bearing Acyclic Secondary Alkyl Groups by Suzuki-Miyaura Cross-Couplings[J]. Angew. Chem.-Int. Edit.,2015,54(12):3792-3796.
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