SIOC OpenIR  > 金属有机化学国家重点实验室
Highly Enantioselective Nickel-Catalyzed Intramolecular Reductive Cyclization of Alkynones
Alternative Title高立体选择性的分子内炔酮的还原环化
Fu WZ(付文振); Nie M(聂明); Wang AZ(王爱珍); Cao ZP(曹子平); Tang WJ(汤文军)
2015
Source PublicationAngew. Chem.-Int. Edit.
Volume54Issue:8Pages:2520-2524
AbstractThe first asymmetric nickel-catalyzed intramolecular reductive cyclization of alkynones is reported. A P-chiral monophosphine and triethylsilane were used as the ligand and the reducing reagent, respectively, to form a series of tertiary allylic alcohols bearing furan/pyran rings in excellent yields and enantioselectivities. This reaction has a broad substrate scope and enabled the efficient synthesis of dehydroxycubebin and chiral dibenzocyclooctadiene skeletons.
Subtype论文
Subject Area金属有机化学
DOI10.1002/anie.201410700
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000350100000040
Citation statistics
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39569
Collection金属有机化学国家重点实验室
Corresponding AuthorTang WJ(汤文军)
Affiliation中科院上海有机化学研究所, 生命有机化学国家重点实验室
Recommended Citation
GB/T 7714
Fu WZ,Nie M,Wang AZ,et al. Highly Enantioselective Nickel-Catalyzed Intramolecular Reductive Cyclization of Alkynones[J]. Angew. Chem.-Int. Edit.,2015,54(8):2520-2524.
APA 付文振,聂明,王爱珍,曹子平,&汤文军.(2015).Highly Enantioselective Nickel-Catalyzed Intramolecular Reductive Cyclization of Alkynones.Angew. Chem.-Int. Edit.,54(8),2520-2524.
MLA 付文振,et al."Highly Enantioselective Nickel-Catalyzed Intramolecular Reductive Cyclization of Alkynones".Angew. Chem.-Int. Edit. 54.8(2015):2520-2524.
Files in This Item:
File Name/Size DocType Version Access License
2015090.pdf(871KB)期刊论文作者接受稿开放获取CC BY-NC-SAApplication Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[付文振]'s Articles
[聂明]'s Articles
[王爱珍]'s Articles
Baidu academic
Similar articles in Baidu academic
[付文振]'s Articles
[聂明]'s Articles
[王爱珍]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[付文振]'s Articles
[聂明]'s Articles
[王爱珍]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.