| Copper(I)/SaBOX catalyzed highly diastereo- and enantio-selective cyclopropanation of cis-1,2-disubstituted olefins with alpha-nitrodiazoacetates | |
| Alternative Title | 铜(I)/SaBOX催化的顺-1,2-二取代烯烃与α-硝基乙酸酯的高非对映选择性和高对映选择性的环丙烷化反应 |
| Feng LW(冯良文)1; Wang P(王盼)1; Wang LJ(王丽佳)1; Tang Y(唐勇)1 | |
| 2015 | |
| Source Publication | Sci. Bull.
 |
| Volume | 60Issue:2Pages:210-215 |
| Abstract | A copper-catalyzed highly stereoselective cyclopropanation of 1,2-disubstituted olefins with alpha-nitrodiazo acetates has been developed, giving the desired products in up to 97 % yields, up to > 99/1 dr and up to 98 % ee, which provides an efficient access to the synthesis of optical active cyclopropane alpha-amino acids and unnatural alpha-amino acid derivatives. |
| Subtype | 论文 |
| Subject Area | 金属有机化学 |
| DOI | 10.1007/s11434-014-0708-5 |
| URL | 查看原文 |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000348927000006 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sioc.ac.cn/handle/331003/39568 |
| Collection | 金属有机化学国家重点实验室 |
| Corresponding Author | Tang Y(唐勇) |
| Affiliation | 1.中科院上海有机化学研究所, 金属有机化学国家重点实验室 2.天津化学化工协同创新中心 |
| Recommended Citation GB/T 7714 | Feng LW,Wang P,Wang LJ,et al. Copper(I)/SaBOX catalyzed highly diastereo- and enantio-selective cyclopropanation of cis-1,2-disubstituted olefins with alpha-nitrodiazoacetates[J]. Sci. Bull.,2015,60(2):210-215. |
| APA | 冯良文,王盼,王丽佳,&唐勇.(2015).Copper(I)/SaBOX catalyzed highly diastereo- and enantio-selective cyclopropanation of cis-1,2-disubstituted olefins with alpha-nitrodiazoacetates.Sci. Bull.,60(2),210-215. |
| MLA | 冯良文,et al."Copper(I)/SaBOX catalyzed highly diastereo- and enantio-selective cyclopropanation of cis-1,2-disubstituted olefins with alpha-nitrodiazoacetates".Sci. Bull. 60.2(2015):210-215. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 2015081.pdf（350KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | Application Full Text | |
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