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Copper(I)/SaBOX catalyzed highly diastereo- and enantio-selective cyclopropanation of cis-1,2-disubstituted olefins with alpha-nitrodiazoacetates
Alternative Title铜(I)/SaBOX催化的顺-1,2-二取代烯烃与α-硝基乙酸酯的高非对映选择性和高对映选择性的环丙烷化反应
Feng LW(冯良文)1; Wang P(王盼)1; Wang LJ(王丽佳)1; Tang Y(唐勇)1
2015
Source PublicationSci. Bull.
Volume60Issue:2Pages:210-215
AbstractA copper-catalyzed highly stereoselective cyclopropanation of 1,2-disubstituted olefins with alpha-nitrodiazo acetates has been developed, giving the desired products in up to 97 % yields, up to > 99/1 dr and up to 98 % ee, which provides an efficient access to the synthesis of optical active cyclopropane alpha-amino acids and unnatural alpha-amino acid derivatives.
Subtype论文
Subject Area金属有机化学
DOI10.1007/s11434-014-0708-5
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000348927000006
Citation statistics
Cited Times:14[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39568
Collection金属有机化学国家重点实验室
Corresponding AuthorTang Y(唐勇)
Affiliation1.中科院上海有机化学研究所, 金属有机化学国家重点实验室
2.天津化学化工协同创新中心
Recommended Citation
GB/T 7714
Feng LW,Wang P,Wang LJ,et al. Copper(I)/SaBOX catalyzed highly diastereo- and enantio-selective cyclopropanation of cis-1,2-disubstituted olefins with alpha-nitrodiazoacetates[J]. Sci. Bull.,2015,60(2):210-215.
APA 冯良文,王盼,王丽佳,&唐勇.(2015).Copper(I)/SaBOX catalyzed highly diastereo- and enantio-selective cyclopropanation of cis-1,2-disubstituted olefins with alpha-nitrodiazoacetates.Sci. Bull.,60(2),210-215.
MLA 冯良文,et al."Copper(I)/SaBOX catalyzed highly diastereo- and enantio-selective cyclopropanation of cis-1,2-disubstituted olefins with alpha-nitrodiazoacetates".Sci. Bull. 60.2(2015):210-215.
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