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Highly Diastereo- and Enantioselective Palladium-Catalyzed [3+2] Cycloaddition of Vinyl Aziridines and alpha,beta-Unsaturated Ketones
Alternative Title烯基氮杂环丙烷和a,b-不饱和酮的钯催化高非对映选择性, 高对映选择性[3+2]环加成反应
Xu CF(许超凡)1; Zheng BH(郑宝会)1; Suo JJ(索嘉嘉)1; Ding CH(丁昌华)1; Hou XL(侯雪龙)1
2015
Source PublicationAngew. Chem.-Int. Edit.
Volume54Issue:5Pages:1604-1607
AbstractA palladium-catalyzed asymmetric [3+2] cycloaddition reaction of vinylaziridines with alpha,beta-unsaturated ketones, wherein the alkenes have a single activator, is realized in high diastereo- and enantioselectivity, thus affording 3,4-disubstituted pyrrolidines in high yields with excellent ee values. The introduction of a methyl group at C1 of the vinyl group the vinylaziridines greatly improves the stereochemistry of the reaction. A plausible transition state is proposed.
Subtype论文
Subject Area金属有机化学
DOI10.1002/anie.201409467
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000348713900038
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39566
Collection金属有机化学国家重点实验室
Corresponding AuthorDing CH(丁昌华); Hou XL(侯雪龙)
Affiliation1.中科院上海有机化学研究所, 金属有机化学国家重点实验室
2.中科院上海有机化学研究所, 沪港合成化学联合实验室
Recommended Citation
GB/T 7714
Xu CF,Zheng BH,Suo JJ,et al. Highly Diastereo- and Enantioselective Palladium-Catalyzed [3+2] Cycloaddition of Vinyl Aziridines and alpha,beta-Unsaturated Ketones[J]. Angew. Chem.-Int. Edit.,2015,54(5):1604-1607.
APA 许超凡,郑宝会,索嘉嘉,丁昌华,&侯雪龙.(2015).Highly Diastereo- and Enantioselective Palladium-Catalyzed [3+2] Cycloaddition of Vinyl Aziridines and alpha,beta-Unsaturated Ketones.Angew. Chem.-Int. Edit.,54(5),1604-1607.
MLA 许超凡,et al."Highly Diastereo- and Enantioselective Palladium-Catalyzed [3+2] Cycloaddition of Vinyl Aziridines and alpha,beta-Unsaturated Ketones".Angew. Chem.-Int. Edit. 54.5(2015):1604-1607.
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