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学科主题: 金属有机化学
题名: Highly Diastereo- and Enantioselective Palladium-Catalyzed [3+2] Cycloaddition of Vinyl Aziridines and alpha,beta-Unsaturated Ketones
其他题名: 烯基氮杂环丙烷和a,b-不饱和酮的钯催化高非对映选择性, 高对映选择性[3+2]环加成反应
作者: Xu CF(许超凡)1; Zheng BH(郑宝会)1; Suo JJ(索嘉嘉)1; Ding CH(丁昌华)1; Hou XL(侯雪龙)1
通讯作者: 丁昌华 ; 侯雪龙
刊名: Angew. Chem.-Int. Edit.
发表日期: 2015
DOI: 10.1002/anie.201409467
卷: 54, 期:5, 页:1604-1607
收录类别: SCI
文章类型: 论文
英文摘要: A palladium-catalyzed asymmetric [3+2] cycloaddition reaction of vinylaziridines with alpha,beta-unsaturated ketones, wherein the alkenes have a single activator, is realized in high diastereo- and enantioselectivity, thus affording 3,4-disubstituted pyrrolidines in high yields with excellent ee values. The introduction of a methyl group at C1 of the vinyl group the vinylaziridines greatly improves the stereochemistry of the reaction. A plausible transition state is proposed.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000348713900038
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39566
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所, 金属有机化学国家重点实验室
2.中科院上海有机化学研究所, 沪港合成化学联合实验室

Recommended Citation:
Xu CF,Zheng BH,Suo JJ,et al. Highly Diastereo- and Enantioselective Palladium-Catalyzed [3+2] Cycloaddition of Vinyl Aziridines and alpha,beta-Unsaturated Ketones[J]. Angew. Chem.-Int. Edit.,2015,54(5):1604-1607.
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