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A Scandium Complex Bearing Both Methylidene and Phosphinidene Ligands: Synthesis, Structure, and Reactivity
其他题名一个含亚甲基和膦宾配体的钪配合物: 合成、结构和反应性能
Zhou JL(周吉亮)1; Li TF(李腾飞)1; MARON LAURENT1; Leng XB(冷雪冰)1; Chen YF(陈耀峰)1
2015
发表期刊Organometallics
卷号34期号:2页码:470-476
摘要The scandium complex bearing both methylidene and phosphinidene ligands, [(LSc)2(mu(2)-CH2)(mu(2)-PDIPP)] (L = [MeC(NDIPP)CHC(NDIPP)Me](-), DIPP = 2,6-(Pr-i)(2)C6H3) (2), has been synthesized, and its reactivity has been investigated. Reaction of scandium methyl phosphide [LSc(Me){P(H)DIPP}] with 1 equiv of scandium dimethyl complex [LScMe2] in toluene at 60 degrees C provided complex 2 in good yield, and the structure of complex 2 was determined by single-crystal X-ray diffraction. Complex 2 easily undergoes nucleophilic addition reactions with CO2, CS2, benzonitrile, and tert-butyl isocyanide. In the above reactions, the unsaturated substrates insert into the Sc-C(methylidene) bond to give some interesting dianionic ligands while the Sc-P(phosphinidene) bond remains untouched. The bonding situation of complex 2 was analyzed using DFT methods, indicating a more covalent bond between the scandium ion and the phosphinidene ligand than between the scandium ion and the methylidene ligand.
文章类型论文
学科领域金属有机化学
DOI10.1021/om500997j
URL查看原文
收录类别SCI
语种英语
WOS记录号WOS:000348619700010
引用统计
被引频次:23[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/39565
专题金属有机化学国家重点实验室
通讯作者MARON LAURENT; Chen YF(陈耀峰)
作者单位1.中科院上海有机化学研究所, 金属有机化学国家重点实验室
2.法国图卢兹第三大学
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Zhou JL,Li TF,MARON LAURENT,et al. A Scandium Complex Bearing Both Methylidene and Phosphinidene Ligands: Synthesis, Structure, and Reactivity[J]. Organometallics,2015,34(2):470-476.
APA 周吉亮,李腾飞,MARON LAURENT,冷雪冰,&陈耀峰.(2015).A Scandium Complex Bearing Both Methylidene and Phosphinidene Ligands: Synthesis, Structure, and Reactivity.Organometallics,34(2),470-476.
MLA 周吉亮,et al."A Scandium Complex Bearing Both Methylidene and Phosphinidene Ligands: Synthesis, Structure, and Reactivity".Organometallics 34.2(2015):470-476.
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