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学科主题: 金属有机化学
题名: Gold(I)-Catalyzed 1,2-Acyloxy Migration/[3+2] Cycloaddition of 1,6-Diynes with an Ynamide Propargyl Ester Moiety: Highly Efficient Synthesis of Functionalized Cyclopenta[b]indoles
其他题名: 含炔胺炔丙基酯结构的1,6-二炔类底物的金催化1,2-酰氧基迁移/[3+2]环加成反应:官能化环戊烯并[b]吲哚的高效合成
作者: Liu J(刘俊); Chen M(陈铭); Zhang LW(张良伟); Liu YH(刘元红)
通讯作者: 刘元红
刊名: Chem.-Eur. J.
发表日期: 2015
DOI: 10.1002/chem.201405965
卷: 21, 期:3, 页:1009-1013
收录类别: SCI
文章类型: 论文
英文摘要: A gold-catalyzed cycloisomerization of 1,6-diynes containing an ynamide propargyl ester or carbonate moiety has been developed that provides an attractive route to a diverse-substituted 3-acyloxy-1,4-dihydrocyclopenta[b]indoles. Mechanistic studies indicate that the reaction likely proceeds through a competitive 1,2-OAc migration followed by [3+2] cycloaddition of the vinyl gold-carbenoid intermediate with the pendant triple bond. The synthetic utility of the obtained cyclopenta[b]indole products was demonstrated by their efficient transformations by deprotection or double-bond isomerization reactions.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000347615200013
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39559
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 金属有机化学国家重点实验室

Recommended Citation:
Liu J,Chen M,Zhang LW,et al. Gold(I)-Catalyzed 1,2-Acyloxy Migration/[3+2] Cycloaddition of 1,6-Diynes with an Ynamide Propargyl Ester Moiety: Highly Efficient Synthesis of Functionalized Cyclopenta[b]indoles[J]. Chem.-Eur. J.,2015,21(3):1009-1013.
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