中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 金属有机化学国家重点实验室  > 期刊论文
学科主题: 金属有机化学
题名: Zirconium-Mediated Multicomponent Reactions of 1,3-Butadiynes with Ylidenemalononitriles to Form Functionalized 1,8-Naphthyridine and Cyclopenta[b]pyridine Derivatives
其他题名: 锆促进的3-丁二炔与烯基双氰的多组分反应:官能团化1,8-萘啶和环戊烯并[b]吡啶衍生物的形成
作者: Yu SS(俞莎莎); Sun RH(孙仁红); Chen HY(陈好益); Jie X(解鑫); Liu YH(刘元红)
通讯作者: 刘元红
刊名: Chem.-Eur. J.
发表日期: 2015
DOI: 10.1002/chem.201405899
卷: 21, 期:4, 页:1420-1424
收录类别: SCI
文章类型: 论文
英文摘要: Zirconocene-mediated multicomponent reactions of 1,3-butadiynes with ylidenemalononitriles in the absence or presence of CuCl have been developed. In the absence of CuCl, 1,3-butadiyne couples with three molecules of ylidenemalononitriles to yield azazirconacycles bearing a hexahydro-1,8-naphthyridine skeleton with high stereoselectivity. In the presence of CuCl, cyclopenta[b]pyridine or cyclopenta[b] quinolin-1-one derivatives are obtained via transmetalation of Zr-C bond to Cu-C bond as the key reaction step. These domino-type reactions proceed with high chemo-, regio- and/or stereoselectivities, and allowing the formation of multiple C-N and C-C bonds in a single operation.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000347841500005
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39558
Appears in Collections:金属有机化学国家重点实验室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2015028.pdf(406KB)期刊论文作者接受稿开放获取View Download

作者单位: 中科院上海有机化学研究所, 金属有机化学国家重点实验室

Recommended Citation:
Yu SS,Sun RH,Chen HY,et al. Zirconium-Mediated Multicomponent Reactions of 1,3-Butadiynes with Ylidenemalononitriles to Form Functionalized 1,8-Naphthyridine and Cyclopenta[b]pyridine Derivatives[J]. Chem.-Eur. J.,2015,21(4):1420-1424.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[俞莎莎]'s Articles
[孙仁红]'s Articles
[陈好益]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[俞莎莎]‘s Articles
[孙仁红]‘s Articles
[陈好益]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2015028.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace