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Zirconium-Mediated Multicomponent Reactions of 1,3-Butadiynes with Ylidenemalononitriles to Form Functionalized 1,8-Naphthyridine and Cyclopenta[b]pyridine Derivatives
Alternative Title锆促进的3-丁二炔与烯基双氰的多组分反应:官能团化1,8-萘啶和环戊烯并[b]吡啶衍生物的形成
Yu SS(俞莎莎); Sun RH(孙仁红); Chen HY(陈好益); Jie X(解鑫); Liu YH(刘元红)
2015
Source PublicationChem.-Eur. J.
Volume21Issue:4Pages:1420-1424
AbstractZirconocene-mediated multicomponent reactions of 1,3-butadiynes with ylidenemalononitriles in the absence or presence of CuCl have been developed. In the absence of CuCl, 1,3-butadiyne couples with three molecules of ylidenemalononitriles to yield azazirconacycles bearing a hexahydro-1,8-naphthyridine skeleton with high stereoselectivity. In the presence of CuCl, cyclopenta[b]pyridine or cyclopenta[b] quinolin-1-one derivatives are obtained via transmetalation of Zr-C bond to Cu-C bond as the key reaction step. These domino-type reactions proceed with high chemo-, regio- and/or stereoselectivities, and allowing the formation of multiple C-N and C-C bonds in a single operation.
Subtype论文
Subject Area金属有机化学
DOI10.1002/chem.201405899
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000347841500005
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39558
Collection金属有机化学国家重点实验室
Corresponding AuthorLiu YH(刘元红)
Affiliation中科院上海有机化学研究所, 金属有机化学国家重点实验室
Recommended Citation
GB/T 7714
Yu SS,Sun RH,Chen HY,et al. Zirconium-Mediated Multicomponent Reactions of 1,3-Butadiynes with Ylidenemalononitriles to Form Functionalized 1,8-Naphthyridine and Cyclopenta[b]pyridine Derivatives[J]. Chem.-Eur. J.,2015,21(4):1420-1424.
APA 俞莎莎,孙仁红,陈好益,解鑫,&刘元红.(2015).Zirconium-Mediated Multicomponent Reactions of 1,3-Butadiynes with Ylidenemalononitriles to Form Functionalized 1,8-Naphthyridine and Cyclopenta[b]pyridine Derivatives.Chem.-Eur. J.,21(4),1420-1424.
MLA 俞莎莎,et al."Zirconium-Mediated Multicomponent Reactions of 1,3-Butadiynes with Ylidenemalononitriles to Form Functionalized 1,8-Naphthyridine and Cyclopenta[b]pyridine Derivatives".Chem.-Eur. J. 21.4(2015):1420-1424.
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