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Gold(I)-Catalyzed 1,4-and/or 1,5-Heteroaryl Migration Reactions through Regiocontrolled Cyclizations
Alternative Title金催化1,4或1,5-杂芳环迁移/区域选择性环化反应
Wang CY(王程宇); Jie X(解鑫); Liu J(刘俊); Liu YH(刘元红); Li YX(李玉学)
2015
Source PublicationChem.-Eur. J.
Volume21Issue:2Pages:559-564
AbstractGold(I)-catalyzed regioselective cycloisomerizations of furan-ynes have been described. The reaction provides a concise access to stereodefined trisubstituted alkenes by endo cyclization with concomitant 1,5-migration of the furanyl group in the presence of unactivated 3 angstrom molecular sieves. In the absence of molecular sieves, indene products are generated by exo cyclization, followed by 1,4-furanyl migration/cyclization. The scope for 1,5-migrations can be extended to other heterocycles, such as benzofurans, thiophenes, and pyrroles.
Subtype论文
Subject Area金属有机化学
DOI10.1002/chem.201405190
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000347231300010
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39554
Collection金属有机化学国家重点实验室
Corresponding AuthorLiu YH(刘元红); Li YX(李玉学)
Affiliation中科院上海有机化学研究所, 金属有机化学国家重点实验室
Recommended Citation
GB/T 7714
Wang CY,Jie X,Liu J,et al. Gold(I)-Catalyzed 1,4-and/or 1,5-Heteroaryl Migration Reactions through Regiocontrolled Cyclizations[J]. Chem.-Eur. J.,2015,21(2):559-564.
APA 王程宇,解鑫,刘俊,刘元红,&李玉学.(2015).Gold(I)-Catalyzed 1,4-and/or 1,5-Heteroaryl Migration Reactions through Regiocontrolled Cyclizations.Chem.-Eur. J.,21(2),559-564.
MLA 王程宇,et al."Gold(I)-Catalyzed 1,4-and/or 1,5-Heteroaryl Migration Reactions through Regiocontrolled Cyclizations".Chem.-Eur. J. 21.2(2015):559-564.
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