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学科主题: 金属有机化学
题名: Gold(I)-Catalyzed 1,4-and/or 1,5-Heteroaryl Migration Reactions through Regiocontrolled Cyclizations
其他题名: 金催化1,4或1,5-杂芳环迁移/区域选择性环化反应
作者: Wang CY(王程宇); Jie X(解鑫); Liu J(刘俊); Liu YH(刘元红); Li YX(李玉学)
通讯作者: 刘元红 ; 李玉学
刊名: Chem.-Eur. J.
发表日期: 2015
DOI: 10.1002/chem.201405190
卷: 21, 期:2, 页:559-564
收录类别: SCI
文章类型: 论文
英文摘要: Gold(I)-catalyzed regioselective cycloisomerizations of furan-ynes have been described. The reaction provides a concise access to stereodefined trisubstituted alkenes by endo cyclization with concomitant 1,5-migration of the furanyl group in the presence of unactivated 3 angstrom molecular sieves. In the absence of molecular sieves, indene products are generated by exo cyclization, followed by 1,4-furanyl migration/cyclization. The scope for 1,5-migrations can be extended to other heterocycles, such as benzofurans, thiophenes, and pyrroles.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000347231300010
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39554
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 金属有机化学国家重点实验室

Recommended Citation:
Wang CY,Jie X,Liu J,et al. Gold(I)-Catalyzed 1,4-and/or 1,5-Heteroaryl Migration Reactions through Regiocontrolled Cyclizations[J]. Chem.-Eur. J.,2015,21(2):559-564.
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