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Chemoselective and fast decarboxylative allylation by photoredox catalysis under mild conditions
Alternative Title化学选择性的快速脱羧烯丙基化反应在温和光催化条件下进行
Hu CC(胡辰辰); Chen YY(陈以昀)
2015
Source PublicationOrg. Chem. Front.
Volume2Issue:10Pages:1352-1355
AbstractHere we report a visible-light-induced decarboxylative allylation to build C(sp(3))- allyl bonds. This allylation reaction works for primary, secondary, tertiary, benzyl, and alpha-heteroatom-substituted alkyl N-acyloxyphthalimides and is compatible with many sensitive functional groups. The reaction is complete in minutes at room temperature and can be run in both organic solvents and neutral aqueous solutions. A series of mechanistic experiments have been implemented and a functional-group-rich oligosaccharide modification is demonstrated with the decarboxylative allylation.
Subtype论文
Subject Area生命有机化学
DOI10.1039/c5qo00187k
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000364450000010
Citation statistics
Cited Times:32[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39539
Collection生命有机化学国家重点实验室
Corresponding AuthorChen YY(陈以昀)
Affiliation中科院上海有机化学研究所, 生命有机化学国家重点实验室
Recommended Citation
GB/T 7714
Hu CC,Chen YY. Chemoselective and fast decarboxylative allylation by photoredox catalysis under mild conditions[J]. Org. Chem. Front.,2015,2(10):1352-1355.
APA 胡辰辰,&陈以昀.(2015).Chemoselective and fast decarboxylative allylation by photoredox catalysis under mild conditions.Org. Chem. Front.,2(10),1352-1355.
MLA 胡辰辰,et al."Chemoselective and fast decarboxylative allylation by photoredox catalysis under mild conditions".Org. Chem. Front. 2.10(2015):1352-1355.
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