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学科主题: 生命有机化学
题名: Chemoselective and fast decarboxylative allylation by photoredox catalysis under mild conditions
其他题名: 化学选择性的快速脱羧烯丙基化反应在温和光催化条件下进行
作者: Hu CC(胡辰辰); Chen YY(陈以昀)
通讯作者: 陈以昀
刊名: Org. Chem. Front.
发表日期: 2015
DOI: 10.1039/c5qo00187k
卷: 2, 期:10, 页:1352-1355
收录类别: SCI
文章类型: 论文
英文摘要: Here we report a visible-light-induced decarboxylative allylation to build C(sp(3))- allyl bonds. This allylation reaction works for primary, secondary, tertiary, benzyl, and alpha-heteroatom-substituted alkyl N-acyloxyphthalimides and is compatible with many sensitive functional groups. The reaction is complete in minutes at room temperature and can be run in both organic solvents and neutral aqueous solutions. A series of mechanistic experiments have been implemented and a functional-group-rich oligosaccharide modification is demonstrated with the decarboxylative allylation.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000364450000010
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39539
Appears in Collections:生命有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 生命有机化学国家重点实验室

Recommended Citation:
Hu CC,Chen YY. Chemoselective and fast decarboxylative allylation by photoredox catalysis under mild conditions[J]. Org. Chem. Front.,2015,2(10):1352-1355.
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