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Total Synthesis of Epoxyeujindole A
Alternative TitleTotal Synthesis of Epoxyeujindole A
Lu ZH(陆钊洪); Li HL(李海龙); Bian M(卞明); Li A(李昂)
2015
Source PublicationJ. Am. Chem. Soc.
Volume137Issue:43Pages:13764-13767
AbstractThe total synthesis of epoxyeujindole A, a structurally unusual indole diterpenoid isolated from Eupenicillium javanicum, has been accomplished for the first time. The synthesis features a late-stage cationic cyclization strategy, which took advantage of an electron-rich olefinic substrate. The CDE ring system was assembled via an enantioselective conjugate addition/alkylation, a Luche cyclization, and a Nozaki-Hiyama-Kishi reaction. The heavily substituted A ring was constructed through a Suzuki-Miyaura coupling and a cationic cyclization, and the bridged fused B ring was formed through a Prins reaction.
Subtype论文
Subject Area生命有机化学
DOI10.1021/jacs.5b09198
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000364355900011
Citation statistics
Cited Times:23[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39536
Collection生命有机化学国家重点实验室
Corresponding AuthorLi A(李昂)
Affiliation中科院上海有机化学研究所, 生命有机化学国家重点实验室
Recommended Citation
GB/T 7714
Lu ZH,Li HL,Bian M,et al. Total Synthesis of Epoxyeujindole A[J]. J. Am. Chem. Soc.,2015,137(43):13764-13767.
APA 陆钊洪,李海龙,卞明,&李昂.(2015).Total Synthesis of Epoxyeujindole A.J. Am. Chem. Soc.,137(43),13764-13767.
MLA 陆钊洪,et al."Total Synthesis of Epoxyeujindole A".J. Am. Chem. Soc. 137.43(2015):13764-13767.
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