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Synthesis and Structural Reassignment of Plakinidone
Alternative TitlePlakinidone的合成及结构更正
Xu ZJ(徐泽军); Tan DX(谈东兴); Wu YK(伍贻康)
Source PublicationOrg. Lett.
AbstractIn connection with its first synthesis, plakinidone was structurally revised to a five-membered lac-tone. The key evidence for the previous assignment of this natural product as a perlactone was proven to be a misinterpretation of the MS data because of unawareness of a facile air oxidation. The synthetic samples also allowed for detection of differences in C-13 NMR for diastereomers of remote stereogenic centers, along with the influence of the air oxidation on the optical rotation.
Subject Area生命有机化学
Indexed BySCI
WOS IDWOS:000363225000041
Citation statistics
Cited Times:10[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Corresponding AuthorWu YK(伍贻康)
Affiliation中科院上海有机化学研究所, 生命有机化学国家重点实验室
Recommended Citation
GB/T 7714
Xu ZJ,Tan DX,Wu YK. Synthesis and Structural Reassignment of Plakinidone[J]. Org. Lett.,2015,17(20):5092-5095.
APA 徐泽军,谈东兴,&伍贻康.(2015).Synthesis and Structural Reassignment of Plakinidone.Org. Lett.,17(20),5092-5095.
MLA 徐泽军,et al."Synthesis and Structural Reassignment of Plakinidone".Org. Lett. 17.20(2015):5092-5095.
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